Angewandte Chemie - International Edition, volume 59, issue 13, pages 5116-5122
Molecular Porous Photosystems Tailored for Long‐Term Photocatalytic CO 2 Reduction
Mathis Duguet
2
,
Quentin Perrinet
3
,
Ashta C Ghosh
1
,
Marcelo Alves Favaro
1, 4
,
Yorck Mohr
1
,
Chantal Lorentz
1
,
Regina Palkovits
4
,
David Farrusseng
1
,
V. De Waele
3
,
1
Université de LyonUniversité Claude Bernard Lyon 1CNRS, IRCELYON—UMR 5256 2 Avenue Albert Einstein 69626 Villeurbanne Cedex France
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3
5
Université de LyonUniversité Claude Bernard Lyon 1, CPE LyonCNRS, C2P2—UMR 5265 43 Bvd du 11 Novembre 1918 69616 Villeurbanne France
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Publication type: Journal Article
Publication date: 2020-03-23
scimago Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
PubMed ID:
31945254
General Chemistry
Catalysis
Abstract
Porous organic polymers were used as photosystems to deliver a constant production rate for the CO2 to formate reduction for several days. Their photoactivation pathway is presented, including an ultrafast electronic energy transfer from the photosensitizer to the catalyst as evidenced by time-resolved spectroscopy and quantum mechanical calculations.
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