Angewandte Chemie - International Edition, volume 59, issue 13, pages 5116-5122

Molecular Porous Photosystems Tailored for Long‐Term Photocatalytic CO 2 Reduction

Mathis Duguet 2
Quentin Perrinet 3
Ashta C Ghosh 1
Marcelo Alves Favaro 1, 4
Yorck Mohr 1
Chantal Lorentz 1
Regina Palkovits 4
David Farrusseng 1
V. De Waele 3
Show full list: 13 authors
Publication typeJournal Article
Publication date2020-03-23
scimago Q1
SJR5.300
CiteScore26.6
Impact factor16.1
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
Porous organic polymers were used as photosystems to deliver a constant production rate for the CO2 to formate reduction for several days. Their photoactivation pathway is presented, including an ultrafast electronic energy transfer from the photosensitizer to the catalyst as evidenced by time-resolved spectroscopy and quantum mechanical calculations.
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