Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst
Publication type: Journal Article
Publication date: 2021-01-26
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
33301240
General Chemistry
Catalysis
Abstract
A readily available catalyst consisting of iron dichloride in combination with 1,10-phenanthroline catalyzes the ring-closing C-H amination of N-benzoyloxyurea to form imidazolidin-2-ones in high yields. The C-H amination reaction is very general and applicable to benzylic, allylic, propargylic, and completely non-activated aliphatic C(sp3 )-H bonds, and it also works for C(sp2 )-H bonds. The surprisingly simple method can be performed under open flask conditions.
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37
Total citations:
37
Citations from 2024:
13
(35%)
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GOST
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Jarrige L. et al. Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 12. pp. 6314-6319.
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Jarrige L., Zhou Z., Hemming M., Meggers E. Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 12. pp. 6314-6319.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.202013687
UR - https://doi.org/10.1002/anie.202013687
TI - Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst
T2 - Angewandte Chemie - International Edition
AU - Jarrige, Lucie
AU - Zhou, Zijun
AU - Hemming, Marcel
AU - Meggers, E.
PY - 2021
DA - 2021/01/26
PB - Wiley
SP - 6314-6319
IS - 12
VL - 60
PMID - 33301240
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Jarrige,
author = {Lucie Jarrige and Zijun Zhou and Marcel Hemming and E. Meggers},
title = {Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst},
journal = {Angewandte Chemie - International Edition},
year = {2021},
volume = {60},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.202013687},
number = {12},
pages = {6314--6319},
doi = {10.1002/anie.202013687}
}
Cite this
MLA
Copy
Jarrige, Lucie, et al. “Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst.” Angewandte Chemie - International Edition, vol. 60, no. 12, Jan. 2021, pp. 6314-6319. https://doi.org/10.1002/anie.202013687.