Angewandte Chemie - International Edition, volume 60, issue 40, pages 21979-21987

Highly Efficient CO ₂ Electroreduction to Methanol through Atomically Dispersed Sn Coupled with Defective CuO Catalysts

Weiwei Guo ^{1, 2}

Shoujie Liu ³

Xingxing Tan ^{1, 2}

RUIZHI WU ^{1, 2}

Xupeng Yan ^{1, 2}

Chunjun Chen ¹

Qinggong Zhu ¹

Li-Rong Zheng ⁴

Jingyuan Ma ⁵

Jian Zhang ⁴

YUYING HUANG ⁵

Xiaofu Sun ^{1, 2}

Buxing Han ^{1, 2, 6, 7}

Show full list: 13 authors

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Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Colloid and Interface and Thermodynamics CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Zhongguancun North First Street 2 Beijing 100190 China

School of Chemistry and Chemical Engineering University of Chinese Academy of Sciences Yuquan Road, ShijingshanDistrict Beijing 100049 China |

Chemistry and Chemical Engineering of Guangdong Laboratory Shantou 515063 China |

⁴

Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China |

⁵

Shanghai Synchrotron Radiation Facility, Zhangjiang Laboratory (SSRF, ZJLab) Shanghai Advanced Research Institute Chinese Academy of Sciences Shanghai 201204 China |

⁶

Physical Science Laboratory Huairou National Comprehensive Science Center Beijing 101400 China |

⁷

Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University Shanghai 200062 China |

Publication type: Journal Article

Publication date: 2021-08-27

Wiley

Journal: Angewandte Chemie - International Edition

scimago Q1

SJR: 5.300

CiteScore: 26.6

Impact factor: 16.1

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202108635

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PubMed ID: 34346160

General Chemistry

Catalysis

Abstract

We have prepared atomically dispersed Sn catalysts on defective CuO for CO2 electroreduction to methanol. The Faradaic efficiency of methanol could reach 88.6 % with a current density of 67.0 mA cm−2. The catalyst was beneficial for CO2 activation via decreasing the energy barrier of *COOH dissociation to form *CO. The *CO was then bound to the Cu species for further reduction, leading to high selectivity toward methanol.

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Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

SJR

5.300

CiteScore

26.6

Impact factor

16.1

ISSN

14337851 (Print)

15213773 (Electronic)

Highly Efficient CO ₂ Electroreduction to Methanol through Atomically Dispersed Sn Coupled with Defective CuO Catalysts

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Highly Efficient CO ₂ Electroreduction to Methanol through Atomically Dispersed Sn Coupled with Defective CuO Catalysts