Wiley
Journal of Applied Polymer Science
,  volume 136 ,  issue 26 ,  pages 47681

Silicon core–iron siloxane shell nanoparticle polymer composites with multiferroic properties

A I Aleksandrov 1, 2
, 
V.G. Shevchenko 1
, 
Ivan A Aleksandrov 1
, 
I A Aleksandrov 2
, 
N A Tebeneva 1, 2
, 
Ivan B Meshkov 1
, 
I B Meshkov 2
, 
A A Kalinina 1, 2
, 
E N Degtyarev 3, 4
, 
A A Dubinskii 3, 4
, 
A L Kovarsky 5, 6
, 
S.B. Zezin 7
, 
V G Krasovskii 8, 9
, 
S. S. Abramchuk 10
, 
M. I. Buzin 10
, 
Aziz M. Muzafarov 10
, 
A M Muzafarov 11
1
 
2
 
3
 
4
 
5
 
6
 
7
 
8
 
9
 
10
 
11
 
Publication type: Journal Article
Publication date: 2019-03-21
Wiley
scimago Q2
wos Q3
SJR: 0.572
CiteScore: 5.8
Impact factor: 2.8
ISSN: 00218995, 10974628
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Polymers and Plastics
Abstract
ABSTRACT

Multiferroic (MF) composites based on nanoparticles consisting of a silica core and a shell of spin‐variable Fe(III) complexes in a polymer matrix (polystyrene) were synthesized and characterized by different methods. The nanoparticles had the formula 80SiO2·20{Fe[OSi(Me)(OEt)2]3}, and their particle size was on the order of 5–7 nm. Dielectric and electron spin resonance studies showed the presence of two types of Fe ions in the nanocomposite. Iron ions in the low‐spin state [Fe(III)‐LS] and iron ions in the high‐spin state [Fe(III)‐HS], which were bound by indirect exchange interactions through oxygen and silicon atoms {[Fe(III)‐LS]─O─Si─O─[Fe(III)‐HS]} were responsible for the MF properties of the composites with core–shell nanoparticles. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47681.

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GOST Copy
Aleksandrov A. I. et al. Silicon core–iron siloxane shell nanoparticle polymer composites with multiferroic properties // Journal of Applied Polymer Science. 2019. Vol. 136. No. 26. p. 47681.
GOST all authors (up to 50) Copy
Aleksandrov A. I., Shevchenko V., Aleksandrov I. A., Aleksandrov I. A., Tebeneva N. A., Meshkov I. B., Meshkov I. B., Kalinina A. A., Degtyarev E. N., Dubinskii A. A., Kovarsky A. L., Zezin S., Krasovskii V. G., Abramchuk S. S., Buzin M. I., Muzafarov A. M., Muzafarov A. M. Silicon core–iron siloxane shell nanoparticle polymer composites with multiferroic properties // Journal of Applied Polymer Science. 2019. Vol. 136. No. 26. p. 47681.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/app.47681
UR - https://onlinelibrary.wiley.com/doi/10.1002/app.47681
TI - Silicon core–iron siloxane shell nanoparticle polymer composites with multiferroic properties
T2 - Journal of Applied Polymer Science
AU - Aleksandrov, A I
AU - Shevchenko, V.G.
AU - Aleksandrov, Ivan A
AU - Aleksandrov, I A
AU - Tebeneva, N A
AU - Meshkov, Ivan B
AU - Meshkov, I B
AU - Kalinina, A A
AU - Degtyarev, E N
AU - Dubinskii, A A
AU - Kovarsky, A L
AU - Zezin, S.B.
AU - Krasovskii, V G
AU - Abramchuk, S. S.
AU - Buzin, M. I.
AU - Muzafarov, Aziz M.
AU - Muzafarov, A M
PY - 2019
DA - 2019/03/21
PB - Wiley
SP - 47681
IS - 26
VL - 136
SN - 0021-8995
SN - 1097-4628
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Aleksandrov,
author = {A I Aleksandrov and V.G. Shevchenko and Ivan A Aleksandrov and I A Aleksandrov and N A Tebeneva and Ivan B Meshkov and I B Meshkov and A A Kalinina and E N Degtyarev and A A Dubinskii and A L Kovarsky and S.B. Zezin and V G Krasovskii and S. S. Abramchuk and M. I. Buzin and Aziz M. Muzafarov and A M Muzafarov},
title = {Silicon core–iron siloxane shell nanoparticle polymer composites with multiferroic properties},
journal = {Journal of Applied Polymer Science},
year = {2019},
volume = {136},
publisher = {Wiley},
month = {mar},
url = {https://onlinelibrary.wiley.com/doi/10.1002/app.47681},
number = {26},
pages = {47681},
doi = {10.1002/app.47681}
}
MLA
Cite this
MLA Copy
Aleksandrov, A. I., et al. “Silicon core–iron siloxane shell nanoparticle polymer composites with multiferroic properties.” Journal of Applied Polymer Science, vol. 136, no. 26, Mar. 2019, p. 47681. https://onlinelibrary.wiley.com/doi/10.1002/app.47681.