Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation
Publication type: Journal Article
Publication date: 2016-07-01
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
27363588
General Chemistry
Catalysis
Organic Chemistry
Abstract
A cyclic (alkyl)(amino)carbene (CAAC) was found to undergo unprecedented rearrangements and transformations of its core structure in the presence of Group 1 and 2 metals. Although the carbene was also found to be prone to intramolecular C-H activation, it was competent for intermolecular activation of a variety of sp-, sp(2) -, and sp(3) -hybridized C-H bonds. Double C-F activation of hexafluorobenzene was also observed in this work. These processes all hold relevance to the role of these carbenes in catalysis, as well as to their use in the synthesis of new and unusual main group or transition metal complexes.
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Total citations:
97
Citations from 2024:
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(16.5%)
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GOST
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Turner Z. R. Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation // Chemistry - A European Journal. 2016. Vol. 22. No. 32. pp. 11461-11468.
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Turner Z. R. Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation // Chemistry - A European Journal. 2016. Vol. 22. No. 32. pp. 11461-11468.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.201602264
UR - https://doi.org/10.1002/chem.201602264
TI - Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation
T2 - Chemistry - A European Journal
AU - Turner, Zoë R.
PY - 2016
DA - 2016/07/01
PB - Wiley
SP - 11461-11468
IS - 32
VL - 22
PMID - 27363588
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Turner,
author = {Zoë R. Turner},
title = {Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation},
journal = {Chemistry - A European Journal},
year = {2016},
volume = {22},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/chem.201602264},
number = {32},
pages = {11461--11468},
doi = {10.1002/chem.201602264}
}
Cite this
MLA
Copy
Turner, Zoë R.. “Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation.” Chemistry - A European Journal, vol. 22, no. 32, Jul. 2016, pp. 11461-11468. https://doi.org/10.1002/chem.201602264.