Chemistry - A European Journal, volume 26, issue 25, pages 5629-5638
Towards molecular design of spin-crossover complexes of 2,6-bis(pyrazol-3-yl)pyridines.
Nikovskiy Igor
1
,
Polezhaev Alexander
1, 2
,
Novikov Valentin V
1, 3
,
Aleshin Dmitry
1, 4
,
Pavlov Alexander
1, 3
,
Saffiulina Elnara
1, 4
,
Aysin Rinat
1, 3
,
Nodaraki Lydia
6
,
Tuna Floriana
6
,
Nelyubina Yulia V.
1, 2
Publication type: Journal Article
Publication date: 2020-03-12
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Molecular design of spin-crossover complexes relies on controlling the spin state of a transition metal ion by proper chemical modifications of the ligands. Here we report the first N,N'-disubstituted 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) that, against the common wisdom, induce a spin-crossover in otherwise high-spin iron(II) complexes by increasing the steric demand of a bulky substituent, an ortho-functionalized phenyl group. As N,N'-disubstituted 3-bpp complexes have no pendant NH groups that make their spin state extremely sensitive to the environment, the proposed ligand design, which may be applicable to isomeric 1-bpp or other families of popular bi-, tri- and higher denticity ligands, opens the way for their molecular design as spin-crossover compounds for future breakthrough applications.
Citations by journals
|
1
2
3
4
5
6
7
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
7 publications, 25%
|
|
Inorganic Chemistry
|
Inorganic Chemistry
4 publications, 14.29%
|
|
Dalton Transactions
|
Dalton Transactions
3 publications, 10.71%
|
|
Crystals
|
Crystals
2 publications, 7.14%
|
|
Russian Chemical Bulletin
|
Russian Chemical Bulletin
2 publications, 7.14%
|
|
Chemistry - A European Journal
|
Chemistry - A European Journal
2 publications, 7.14%
|
|
ACS Omega
|
ACS Omega
1 publication, 3.57%
|
|
Magnetochemistry
|
Magnetochemistry
1 publication, 3.57%
|
|
European Journal of Inorganic Chemistry
|
European Journal of Inorganic Chemistry
1 publication, 3.57%
|
|
Physical Chemistry Chemical Physics
|
Physical Chemistry Chemical Physics
1 publication, 3.57%
|
|
Journal of Materials Chemistry C
|
Journal of Materials Chemistry C
1 publication, 3.57%
|
|
Chemical Science
|
Chemical Science
1 publication, 3.57%
|
|
Molecules
|
Molecules
1 publication, 3.57%
|
|
ChemCatChem
|
ChemCatChem
1 publication, 3.57%
|
|
1
2
3
4
5
6
7
|
Citations by publishers
|
1
2
3
4
5
6
7
|
|
|
Pleiades Publishing
|
Pleiades Publishing
7 publications, 25%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
6 publications, 21.43%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
5 publications, 17.86%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 14.29%
|
|
Wiley
|
Wiley
4 publications, 14.29%
|
|
Springer Nature
|
Springer Nature
2 publications, 7.14%
|
|
1
2
3
4
5
6
7
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[0,0,0,0,0],"codes":[0,0,0,0,0],"imageUrls":["","","","",""],"datasets":[{"label":"Citations number","data":[5,8,8,5,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["17.86","28.57","28.57","17.86","7.14"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Russian Journal of Coordination Chemistry\/Koordinatsionnaya Khimiya","Inorganic Chemistry","Dalton Transactions","Crystals","Russian Chemical Bulletin","Chemistry - A European Journal","ACS Omega","Magnetochemistry","European Journal of Inorganic Chemistry","Physical Chemistry Chemical Physics","Journal of Materials Chemistry C","Chemical Science","Molecules","ChemCatChem"],"ids":[12054,24714,8473,15823,10918,24708,18901,25379,15359,1773,3848,9646,1770,10149],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[7,4,3,2,2,2,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[25,14.29,10.71,7.14,7.14,7.14,3.57,3.57,3.57,3.57,3.57,3.57,3.57,3.57],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Pleiades Publishing","Royal Society of Chemistry (RSC)","American Chemical Society (ACS)","Multidisciplinary Digital Publishing Institute (MDPI)","Wiley","Springer Nature"],"ids":[101,123,40,202,11,8],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[7,6,5,4,4,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[25,21.43,17.86,14.29,14.29,7.14],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Nikovskiy I. et al. Towards molecular design of spin-crossover complexes of 2,6-bis(pyrazol-3-yl)pyridines. // Chemistry - A European Journal. 2020. Vol. 26. No. 25. pp. 5629-5638.
GOST all authors (up to 50)
Copy
Nikovskiy I., Polezhaev A., Novikov V. V., Aleshin D., Pavlov A., Saffiulina E., Aysin R., Dorovatovskii P., Nodaraki L., Tuna F., Nelyubina Y. V. Towards molecular design of spin-crossover complexes of 2,6-bis(pyrazol-3-yl)pyridines. // Chemistry - A European Journal. 2020. Vol. 26. No. 25. pp. 5629-5638.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.202000047
UR - https://doi.org/10.1002%2Fchem.202000047
TI - Towards molecular design of spin-crossover complexes of 2,6-bis(pyrazol-3-yl)pyridines.
T2 - Chemistry - A European Journal
AU - Nikovskiy, Igor
AU - Saffiulina, Elnara
AU - Aysin, Rinat
AU - Nodaraki, Lydia
AU - Aleshin, Dmitry
AU - Nelyubina, Yulia V.
AU - Polezhaev, Alexander
AU - Novikov, Valentin V
AU - Pavlov, Alexander
AU - Dorovatovskii, Pavel
AU - Tuna, Floriana
PY - 2020
DA - 2020/03/12 00:00:00
PB - Wiley
SP - 5629-5638
IS - 25
VL - 26
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex
Copy
@article{2020_Nikovskiy,
author = {Igor Nikovskiy and Elnara Saffiulina and Rinat Aysin and Lydia Nodaraki and Dmitry Aleshin and Yulia V. Nelyubina and Alexander Polezhaev and Valentin V Novikov and Alexander Pavlov and Pavel Dorovatovskii and Floriana Tuna},
title = {Towards molecular design of spin-crossover complexes of 2,6-bis(pyrazol-3-yl)pyridines.},
journal = {Chemistry - A European Journal},
year = {2020},
volume = {26},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002%2Fchem.202000047},
number = {25},
pages = {5629--5638},
doi = {10.1002/chem.202000047}
}
Cite this
MLA
Copy
Nikovskiy, Igor, et al. “Towards molecular design of spin-crossover complexes of 2,6-bis(pyrazol-3-yl)pyridines..” Chemistry - A European Journal, vol. 26, no. 25, Mar. 2020, pp. 5629-5638. https://doi.org/10.1002%2Fchem.202000047.