volume 26 issue 53 pages 12188-12193

Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2

Andrey V Mironov 3, 4
Sergey Y Istomin 4, 6
Karina V Birichevskaya 1, 2
Andrey A Gippius 3, 4, 7, 8
Sergey V Zhurenko 3, 4, 7, 8
Tatyana B. Shatalova 3, 4
Publication typeJournal Article
Publication date2020-08-28
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract

Two new cerium(IV) phosphates were obtained: cerium(IV) hydroxidophosphate, Ce(OH)PO4, and cerium(IV) oxidophosphate, Ce2O(PO4)2, which were shown to complement the classes of isostructural compounds M(OH)PO4 and R2O(PO4)2, where M=Th, U and R=Th, U, Np, Zr. Ce2O(PO4)2 oxidophosphate is formed by elimination of H2O from the crystal structure of Ce(OH)PO4 during its thermal decomposition. The structures of Ce(OH)PO4 and Ce2O(PO4)2 are related to each other with the same Cmce space group and similar unit cell parameters (a=6.9691(3) Å, b=9.0655(4) Å, c=12.2214(4) Å, V=772.13(8) Å3, Z=8; a=7.0220(4) Å, b=8.9894(5) Å, c=12.544(1) Å, V=791.8(1) Å3, Z=4, respectively).

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Kozlova T. O. et al. Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2 // Chemistry - A European Journal. 2020. Vol. 26. No. 53. pp. 12188-12193.
GOST all authors (up to 50) Copy
Kozlova T. O., Mironov A. V., Istomin S. Y., Istomin S. Y., Birichevskaya K. V., Gippius A. A., Zhurenko S. V., Shatalova T. B., Baranchikov A. E., Ivanov V. K. Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2 // Chemistry - A European Journal. 2020. Vol. 26. No. 53. pp. 12188-12193.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/chem.202002527
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202002527
TI - Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2
T2 - Chemistry - A European Journal
AU - Kozlova, Taisiya O.
AU - Mironov, Andrey V
AU - Istomin, Sergey Ya.
AU - Istomin, Sergey Y
AU - Birichevskaya, Karina V
AU - Gippius, Andrey A
AU - Zhurenko, Sergey V
AU - Shatalova, Tatyana B.
AU - Baranchikov, Alexander E
AU - Ivanov, Vladimir K.
PY - 2020
DA - 2020/08/28
PB - Wiley
SP - 12188-12193
IS - 53
VL - 26
PMID - 32608019
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Kozlova,
author = {Taisiya O. Kozlova and Andrey V Mironov and Sergey Ya. Istomin and Sergey Y Istomin and Karina V Birichevskaya and Andrey A Gippius and Sergey V Zhurenko and Tatyana B. Shatalova and Alexander E Baranchikov and Vladimir K. Ivanov},
title = {Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2},
journal = {Chemistry - A European Journal},
year = {2020},
volume = {26},
publisher = {Wiley},
month = {aug},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202002527},
number = {53},
pages = {12188--12193},
doi = {10.1002/chem.202002527}
}
MLA
Cite this
MLA Copy
Kozlova, Taisiya O., et al. “Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2.” Chemistry - A European Journal, vol. 26, no. 53, Aug. 2020, pp. 12188-12193. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202002527.