Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials
Тип публикации: Journal Article
Дата публикации: 2022-09-02
scimago Q1
wos Q2
БС1
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
35943830
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
Merging furan rings with 1,2,7-oxa- and -azadiborepins. This modular synthesis proceeds through a reversible ring-opening process and furnishes the novel heteropolyaromatic compounds from a common precursor. The tricyclic systems are overall aromatic, and weak aromaticity in the diboron heterocycles favors π electron delocalization over the bifuran unit. The π-conjugated system is easily extended through the α-positions of the furan rings.
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Bachmann J. et al. Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials // Chemistry - A European Journal. 2022. Vol. 28. No. 63.
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Bachmann J., Helbig A., Crumbach M., Krummenacher I., Braunschweig H., Helten H. J. Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials // Chemistry - A European Journal. 2022. Vol. 28. No. 63.
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TY - JOUR
DO - 10.1002/chem.202202455
UR - https://doi.org/10.1002/chem.202202455
TI - Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials
T2 - Chemistry - A European Journal
AU - Bachmann, Jonas
AU - Helbig, Andreas
AU - Crumbach, Merian
AU - Krummenacher, Ivo
AU - Braunschweig, Holger
AU - Helten, H J
PY - 2022
DA - 2022/09/02
PB - Wiley
IS - 63
VL - 28
PMID - 35943830
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (до 50 авторов)
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@article{2022_Bachmann,
author = {Jonas Bachmann and Andreas Helbig and Merian Crumbach and Ivo Krummenacher and Holger Braunschweig and H J Helten},
title = {Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials},
journal = {Chemistry - A European Journal},
year = {2022},
volume = {28},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.202202455},
number = {63},
doi = {10.1002/chem.202202455}
}