Synthesis of Amorphous Hydrophobic Telechelic Hydrocarbon Diols via ADMET Polymerization
Publication type: Journal Article
Publication date: 2009-10-02
scimago Q2
wos Q3
SJR: 0.569
CiteScore: 4.5
Impact factor: 2.7
ISSN: 10221352, 15213935
Materials Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Amorphous, hydrophobic telechelic hydrocarbon diols were synthesized using acyclic diene metathesis (ADMET) polymerization. These diols can be used in hydrolysis and UV resistant polyurethanes. The hydrocarbon backbone is based on a mimic of an ethylene/isobutylene polymer, made by the ADMET polymerization of a gem-dimethyl substituted α,ω-diene followed by hydrogenation of the polymer's repeat unit unsaturation. Chain termination reactants (CTR's) having one, three, and nine methylene spacers, respectively, between their olefin and alcohol precursor group were used to cap the polymer chain ends to yield 2.0 functional telechelics. Use of the medium length CTR in a polymerization-depolymerization scheme, resulted in amorphous (Tg = -56°C) telechelic diols with good molecular weight control.
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Total citations:
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Citations from 2024:
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(3.7%)
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GOST
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Schwendeman J. E., Wagener K. B. Synthesis of Amorphous Hydrophobic Telechelic Hydrocarbon Diols via ADMET Polymerization // Macromolecular Chemistry and Physics. 2009. Vol. 210. No. 21. pp. 1818-1833.
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Schwendeman J. E., Wagener K. B. Synthesis of Amorphous Hydrophobic Telechelic Hydrocarbon Diols via ADMET Polymerization // Macromolecular Chemistry and Physics. 2009. Vol. 210. No. 21. pp. 1818-1833.
Cite this
RIS
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TY - JOUR
DO - 10.1002/macp.200900270
UR - https://doi.org/10.1002/macp.200900270
TI - Synthesis of Amorphous Hydrophobic Telechelic Hydrocarbon Diols via ADMET Polymerization
T2 - Macromolecular Chemistry and Physics
AU - Schwendeman, John E
AU - Wagener, Kenneth B.
PY - 2009
DA - 2009/10/02
PB - Wiley
SP - 1818-1833
IS - 21
VL - 210
SN - 1022-1352
SN - 1521-3935
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Schwendeman,
author = {John E Schwendeman and Kenneth B. Wagener},
title = {Synthesis of Amorphous Hydrophobic Telechelic Hydrocarbon Diols via ADMET Polymerization},
journal = {Macromolecular Chemistry and Physics},
year = {2009},
volume = {210},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/macp.200900270},
number = {21},
pages = {1818--1833},
doi = {10.1002/macp.200900270}
}
Cite this
MLA
Copy
Schwendeman, John E., and Kenneth B. Wagener. “Synthesis of Amorphous Hydrophobic Telechelic Hydrocarbon Diols via ADMET Polymerization.” Macromolecular Chemistry and Physics, vol. 210, no. 21, Oct. 2009, pp. 1818-1833. https://doi.org/10.1002/macp.200900270.