Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent
Publication type: Journal Article
Publication date: 2013-03-01
scimago Q3
SJR: 0.208
CiteScore: 1.5
Impact factor: —
ISSN: 10221360, 15213900
Materials Chemistry
Organic Chemistry
Condensed Matter Physics
Polymers and Plastics
Abstract
Preparation of PNVCL controlling its molecular weight and maintaining low dispersities by using a trithiocarbonate RAFT agent was achieved. Typical RAFT kinetics were not observed, nevertheless the prepared polymers were reactivated to grow a second hydrophobic poly(hexyl acrylate) block. A series of statistical copolymers of NVCL with N-vinyl pyrrolidone, n-hexyl acrylate, methacrylic acid, 2-(diethylamino)ethyl methacrylate and 2-(methacryloyloxy)benzoic acid with controlled dispersity were also prepared. By this copolymerization method the cloud point temperature of PNVCL was varied from 27 °C to 42 °C depending on comonomer type, content and pH of the aqueous solution.
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Ponce Vargas S. M., Cortez-Lemus N. A., Licea‐Claveríe A. Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent // Macromolecular Symposia. 2013. Vol. 325-326. No. 1. pp. 56-70.
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Ponce Vargas S. M., Cortez-Lemus N. A., Licea‐Claveríe A. Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent // Macromolecular Symposia. 2013. Vol. 325-326. No. 1. pp. 56-70.
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TY - JOUR
DO - 10.1002/masy.201200045
UR - https://doi.org/10.1002/masy.201200045
TI - Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent
T2 - Macromolecular Symposia
AU - Ponce Vargas, Sandra M
AU - Cortez-Lemus, Norma A.
AU - Licea‐Claveríe, Angel
PY - 2013
DA - 2013/03/01
PB - Wiley
SP - 56-70
IS - 1
VL - 325-326
SN - 1022-1360
SN - 1521-3900
ER -
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@article{2013_Ponce Vargas,
author = {Sandra M Ponce Vargas and Norma A. Cortez-Lemus and Angel Licea‐Claveríe},
title = {Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent},
journal = {Macromolecular Symposia},
year = {2013},
volume = {325-326},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/masy.201200045},
number = {1},
pages = {56--70},
doi = {10.1002/masy.201200045}
}
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Ponce Vargas, Sandra M., et al. “Preparation of Poly(N-Vinylcaprolactam) (NVCL) and Statistical Copolymers of NVCL with Variable Cloud Point Temperature by Using A Trithiocarbonate RAFT Agent.” Macromolecular Symposia, vol. 325-326, no. 1, Mar. 2013, pp. 56-70. https://doi.org/10.1002/masy.201200045.