Journal of Polymer Science, Part A: Polymer Chemistry, volume 57, issue 11, pages 1233-1246

Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties

Vysochinskaya Yulia S 1, 2
Peregudov A. S. 2
Orlov Vladimir N 4
Malakhova Yulia 5, 6
Stupnikov Alexey A 5, 6
Buzin M. I. 2
Vasilev Victor G 2
Publication typeJournal Article
Publication date2019-04-11
Quartile SCImago
Quartile WOS
Impact factor
ISSN0887624X, 10990518
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Six new star-shaped polydimethylsiloxane (PDMS) with various cyclic siloxane cores were synthesized by the “grafting onto” method. The polymers obtained feature low dispersity and well-defined structures. Two of them, Q 8-PDMS and D 12-PDMS, have a three-dimensional spatial structure traditional for star-shaped polymers where the arms are arranged in all directions from the branching center. The other four polymers, D 4-PDMS–D 8-PDMS, have quite a different spatial geometry (cis-structure) where all the PDMS-arms are arranged on one side of the branching center plane. Such star-shaped structures were not reported before. The structures and purity of the polymers obtained were confirmed using a set of physicochemical methods of analysis. The effect of the macromolecule structure on the properties of the target polymers was identified.

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Vysochinskaya Y. S. et al. Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties // Journal of Polymer Science, Part A: Polymer Chemistry. 2019. Vol. 57. No. 11. pp. 1233-1246.
GOST all authors (up to 50) Copy
Vysochinskaya Y. S., Anisimov A. A., Peregudov A. S., S. Dubovik A., Orlov V. N., Malakhova Y., Stupnikov A. A., Buzin M. I., Nikiforova G. G., Vasilev V. G., Shchegolikhina O. I., Muzafarov A. M. Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties // Journal of Polymer Science, Part A: Polymer Chemistry. 2019. Vol. 57. No. 11. pp. 1233-1246.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/pola.29380
UR - https://doi.org/10.1002%2Fpola.29380
TI - Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties
T2 - Journal of Polymer Science, Part A: Polymer Chemistry
AU - Vysochinskaya, Yulia S
AU - Stupnikov, Alexey A
AU - Vasilev, Victor G
AU - Shchegolikhina, Olga I.
AU - Anisimov, Anton A.
AU - Peregudov, A. S.
AU - S. Dubovik, Alexander
AU - Orlov, Vladimir N
AU - Malakhova, Yulia
AU - Buzin, M. I.
AU - Nikiforova, Galina G
AU - Muzafarov, Aziz M.
PY - 2019
DA - 2019/04/11 00:00:00
PB - Wiley
SP - 1233-1246
IS - 11
VL - 57
SN - 0887-624X
SN - 1099-0518
ER -
BibTex |
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BibTex Copy
@article{2019_Vysochinskaya,
author = {Yulia S Vysochinskaya and Alexey A Stupnikov and Victor G Vasilev and Olga I. Shchegolikhina and Anton A. Anisimov and A. S. Peregudov and Alexander S. Dubovik and Vladimir N Orlov and Yulia Malakhova and M. I. Buzin and Galina G Nikiforova and Aziz M. Muzafarov},
title = {Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties},
journal = {Journal of Polymer Science, Part A: Polymer Chemistry},
year = {2019},
volume = {57},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002%2Fpola.29380},
number = {11},
pages = {1233--1246},
doi = {10.1002/pola.29380}
}
MLA
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MLA Copy
Vysochinskaya, Yulia S., et al. “Star‐shaped siloxane polymers with various cyclic cores: Synthesis and properties.” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 57, no. 11, Apr. 2019, pp. 1233-1246. https://doi.org/10.1002%2Fpola.29380.
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