pages 3206-3229
Dehydrogenation of Alkanes
Publication type: Reference Entry
Publication date: 2008-02-21
—
Abstract
The sections in this article are
Introduction
Importance of Light Alkenes
Historical Developments
Conceptual Approach
Influence of Temperature on the Equilibrium
Influence of Partial Pressure on the Equilibrium
Energy of Alkane Dehydrogenation
Formation of By‐Products
Removal of Hydrogen to Shift the Equilibrium
Spatial Separation of Dehydrogenation and Hydrogen Combustion
Dehydrogenation and Hydrogen Combustion in a Catalyst Bed
Oxidative Dehydrogenation ( ODH )
Catalytic Systems
Supported Chromia Catalysts
Chromia on Al 2 O 3 Supports
A Structure and Reactivity
B Oxidized State
C Reduced State
D Regeneration
Chromia on Si O 2 / Zr O 2 Supports
Supported Platinum/Tin Catalysts
Platinum as Active Component
Tin as Modifier
State and Mode of Operation of Platinum and Tin
A State of Pt and Sn
B Mode of Operation of Pt and Sn
C Ensemble Effect
D Ligand Effect
Role of the Support
Regeneration of Supported Platinum/Tin Catalysts
A Treatment with Molecular Oxygen
B Treatment with Chlorine
C Treatment with Hydrogen
Kinetics and Mechanism
Kinetics of Dehydrogenation
Chromia/Alumina Catalysts
A Mechanism 1
B Mechanism 2
Platinum and Platinum/Tin Catalysts
Kinetics of Deactivation
Reactor Concepts
Endothermic Character
Preheating the Feed and Carrying out the Reaction in an Adiabatic Reaction System
Carrying Out the Reaction in a Heated Reactor
Preheating the Catalyst and Carrying Out the Reaction in an Adiabatic Reactor
Regeneration
Continuous Systems
Discontinuous Systems
Commercial Processes
UOP Oleflex Process
U hde STAR Process
ABB Lummus CATOFIN Process
Linde PDH Process
S namprogetti‐ Y arsintez FBD Process
Dehydrogenation of Other Alkanes
Dehydrogenation of Heavy n ‐Alkanes
Dehydrogenation of Cyclohexane
Future Developments
Membrane Technology
CO 2 as a Diluent
Conclusions and Future Prospects
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Total citations:
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Citations from 2025:
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(18.52%)