A Novel Class of Ferrocenyl-Aryl-Based Diphosphine Ligands for Rh- and Ru-Catalysed Enantioselective Hydrogenation
Тип публикации: Journal Article
Дата публикации: 2003-01-24
SCImago Q1
WOS Q1
БС1
SJR: 0.704
CiteScore: 6.9
Impact factor: 3.7
ISSN: 16154150, 16154169
General Chemistry
Краткое описание
A series of diphosphines of the novel Walphos ligand family all based on a phenylferrocenylethyl backbone were synthesised in a four-step sequence. In the rhodium- or ruthenium-catalysed asymmetric hydrogenation of olefins and ketones enantioselectivities of up to 95% and 97%, respectively, were obtained. A 2-isopropylcinnamic acid derivative of industrial interest was hydrogenated in 95% ee and with turnover numbers of >5000.
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213
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213
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ГОСТ
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Sturm T., Weissensteiner W., Spindler F. A Novel Class of Ferrocenyl-Aryl-Based Diphosphine Ligands for Rh- and Ru-Catalysed Enantioselective Hydrogenation // Advanced Synthesis and Catalysis. 2003. Vol. 345. No. 12. pp. 160-164.
ГОСТ со всеми авторами (до 50)
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Sturm T., Weissensteiner W., Spindler F. A Novel Class of Ferrocenyl-Aryl-Based Diphosphine Ligands for Rh- and Ru-Catalysed Enantioselective Hydrogenation // Advanced Synthesis and Catalysis. 2003. Vol. 345. No. 12. pp. 160-164.
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TY - JOUR
DO - 10.1002/adsc.200390003
UR - https://doi.org/10.1002/adsc.200390003
TI - A Novel Class of Ferrocenyl-Aryl-Based Diphosphine Ligands for Rh- and Ru-Catalysed Enantioselective Hydrogenation
T2 - Advanced Synthesis and Catalysis
AU - Sturm, Thomas
AU - Weissensteiner, Walter
AU - Spindler, Felix
PY - 2003
DA - 2003/01/24
PB - Wiley
SP - 160-164
IS - 12
VL - 345
SN - 1615-4150
SN - 1615-4169
ER -
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BibTex (до 50 авторов)
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@article{2003_Sturm,
author = {Thomas Sturm and Walter Weissensteiner and Felix Spindler},
title = {A Novel Class of Ferrocenyl-Aryl-Based Diphosphine Ligands for Rh- and Ru-Catalysed Enantioselective Hydrogenation},
journal = {Advanced Synthesis and Catalysis},
year = {2003},
volume = {345},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adsc.200390003},
number = {12},
pages = {160--164},
doi = {10.1002/adsc.200390003}
}
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MLA
Скопировать
Sturm, Thomas, et al. “A Novel Class of Ferrocenyl-Aryl-Based Diphosphine Ligands for Rh- and Ru-Catalysed Enantioselective Hydrogenation.” Advanced Synthesis and Catalysis, vol. 345, no. 12, Jan. 2003, pp. 160-164. https://doi.org/10.1002/adsc.200390003.
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