Angewandte Chemie - International Edition

, volume 56 , issue 20 , pages 5556-5560

Switch in Catalyst State: Single Bifunctional Bi-state Catalyst for Two Different Reactions

Shrivats Semwal ¹

Joyanta Choudhury ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Organometallics & Smart Materials Laboratory, Department of Chemistry; Indian Institute of Science Education and Research Bhopal; Bhopal 462066 India |

Publication type: Journal Article

Publication date: 2017-04-12

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.201702142

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PubMed ID: 28402036

General Chemistry

Catalysis

Abstract

Disclosed here is a molecular switch which responds to acid-base stimuli and serves as a bi-state catalyst for two different reactions. The two states of the switch serve as a highly active and poorly active catalyst for two catalytic reactions (namely a hydrogenation and a dehydrogenative coupling) but in a complementary manner. The system was used in an assisted tandem catalysis set-up involving dehydrogenative coupling of an amine and then hydrogenation of the resulting imine product by switching between the respective states of the catalyst.

Found

1 citation

Chusov Denis

DSc in Chemistry, professor

98 publications, 2 386 citations, 35 reviews

h-index: 25

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

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Semwal S., Choudhury J. Switch in Catalyst State: Single Bifunctional Bi-state Catalyst for Two Different Reactions // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 20. pp. 5556-5560.

GOST all authors (up to 50) Copy

Semwal S., Choudhury J. Switch in Catalyst State: Single Bifunctional Bi-state Catalyst for Two Different Reactions // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 20. pp. 5556-5560.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.201702142

UR - https://doi.org/10.1002/anie.201702142

TI - Switch in Catalyst State: Single Bifunctional Bi-state Catalyst for Two Different Reactions

T2 - Angewandte Chemie - International Edition

AU - Semwal, Shrivats

AU - Choudhury, Joyanta

PY - 2017

DA - 2017/04/12

PB - Wiley

SP - 5556-5560

IS - 20

VL - 56

PMID - 28402036

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2017_Semwal,

author = {Shrivats Semwal and Joyanta Choudhury},

title = {Switch in Catalyst State: Single Bifunctional Bi-state Catalyst for Two Different Reactions},

journal = {Angewandte Chemie - International Edition},

year = {2017},

volume = {56},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/anie.201702142},

number = {20},

pages = {5556--5560},

doi = {10.1002/anie.201702142}

}

MLA

Cite this

MLA Copy

Semwal, Shrivats, and Joyanta Choudhury. “Switch in Catalyst State: Single Bifunctional Bi-state Catalyst for Two Different Reactions.” Angewandte Chemie - International Edition, vol. 56, no. 20, Apr. 2017, pp. 5556-5560. https://doi.org/10.1002/anie.201702142.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)