Angewandte Chemie - International Edition

, volume 60 , issue 12 , pages 6372-6376

Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts

Noy B Nechmad ¹

Victoria Kobernik ¹

Naziha Tarannam ¹

Ravindra S Phatake ¹

Or Eivgi ¹

Sebastian Kozuch ¹

N Gabriel Lemcoff ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry Ben-Gurion University of the Negev Beer-Sheva 84105 Israel |

Ilse Katz Institute for Nanotechnology Science Ben-Gurion University of the Negev Beer-Sheva 84105 Israel |

Publication type: Journal Article

Publication date: 2021-02-12

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202014929

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PubMed ID: 33576565

General Chemistry

Catalysis

Abstract

A diiodo trifluoromethyl sulfur-chelated ruthenium benzylidene complex was synthesized as precatalyst for olefin metathesis, allowing ring-opening metathesis of dicyclopentadiene in the presence of a methylene donor to produce 1,3-divinyl-hexahydropentalenes and depolymerization of polybutadiene upon green light irradiation. The selectivity displayed by the catalyst is attained through a fine balance between its rate of pre-activation and deactivation.

Found

2 citations

Zubkov Fedor

🥼 🤝

DSc in Chemistry, professor

240 publications, 3 228 citations, 19 reviews

h-index: 31

Peoples' Friendship University of Russia

Research interests

Organic Chemistry

2 citations

Antonova Alexandra

PhD in Chemistry

10 publications, 53 citations

h-index: 4

Peoples' Friendship University of Russia

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Organic Chemistry

2 citations

Vasilyev Kirill

4 publications, 29 citations

h-index: 3

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

1 citation

Nikitina Anastasiya

14 publications, 43 citations

h-index: 4

Lomonosov Moscow State University

Moscow Institute of Physics and Technology

1 citation

Logvinenko Nikita

3 publications, 4 citations

h-index: 2

Peoples' Friendship University of Russia

Research interests

Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Computational chemistry

Density functional theory (DFT)

Organic Chemistry

Organic synthesis

Theoretical Chemistry

1 citation

Nikitina Evgeniya

PhD in Chemistry, associate professor

84 publications, 809 citations

h-index: 17

Peoples' Friendship University of Russia

1 citation

Volchkov Nikita

2 publications, 2 citations

h-index: 1

Peoples' Friendship University of Russia

Research interests

Organometallic Chemistry

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GOST |

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GOST Copy

Nechmad N. B. et al. Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 12. pp. 6372-6376.

GOST all authors (up to 50) Copy

Nechmad N. B., Kobernik V., Tarannam N., Phatake R. S., Eivgi O., Kozuch S., Lemcoff N. G. Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 12. pp. 6372-6376.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/anie.202014929

UR - https://doi.org/10.1002/anie.202014929

TI - Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts

T2 - Angewandte Chemie - International Edition

AU - Nechmad, Noy B

AU - Kobernik, Victoria

AU - Tarannam, Naziha

AU - Phatake, Ravindra S

AU - Eivgi, Or

AU - Kozuch, Sebastian

AU - Lemcoff, N Gabriel

PY - 2021

DA - 2021/02/12

PB - Wiley

SP - 6372-6376

IS - 12

VL - 60

PMID - 33576565

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Nechmad,

author = {Noy B Nechmad and Victoria Kobernik and Naziha Tarannam and Ravindra S Phatake and Or Eivgi and Sebastian Kozuch and N Gabriel Lemcoff},

title = {Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts},

journal = {Angewandte Chemie - International Edition},

year = {2021},

volume = {60},

publisher = {Wiley},

month = {feb},

url = {https://doi.org/10.1002/anie.202014929},

number = {12},

pages = {6372--6376},

doi = {10.1002/anie.202014929}

}

MLA

Cite this

MLA Copy

Nechmad, Noy B., et al. “Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts.” Angewandte Chemie - International Edition, vol. 60, no. 12, Feb. 2021, pp. 6372-6376. https://doi.org/10.1002/anie.202014929.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)