A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones
Baode Ma
1
,
Tingting Miao
1
,
Yihua Sun
2
,
Yanmei He
1
,
Ziyi Yu
1
,
Yu Feng
1
,
Hui Cheng Chen
2
,
Qing-Hua Fan
1
Publication type: Journal Article
Publication date: 2014-07-10
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
25042448
General Chemistry
Catalysis
Organic Chemistry
Abstract
Dendron tuning: A series of tunable dendritic BINAP ligands was prepared by attaching polyaryl ether dendrons onto the four phenyl rings on the P atoms and successfully applied in the Ru-catalyzed asymmetric hydrogenation of β-ketoesters, α-ketoesters, and α-ketoamides (see figure). The dendritic wedges were found to be able to effectively tune the asymmetric induction of the catalysts and excellent enantioselectivities were observed with the larger dendrimers.
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37
Total citations:
37
Citations from 2024:
12
(32.44%)
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GOST
Copy
Ma B. et al. A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones // Chemistry - A European Journal. 2014. Vol. 20. No. 32. pp. 9969-9978.
GOST all authors (up to 50)
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Ma B., Miao T., Sun Y., He Y., Yu Z., Feng Yu., Chen H. C., Fan Q. A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones // Chemistry - A European Journal. 2014. Vol. 20. No. 32. pp. 9969-9978.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201402709
UR - https://doi.org/10.1002/chem.201402709
TI - A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones
T2 - Chemistry - A European Journal
AU - Ma, Baode
AU - Miao, Tingting
AU - Sun, Yihua
AU - He, Yanmei
AU - Yu, Ziyi
AU - Feng, Yu
AU - Chen, Hui Cheng
AU - Fan, Qing-Hua
PY - 2014
DA - 2014/07/10
PB - Wiley
SP - 9969-9978
IS - 32
VL - 20
PMID - 25042448
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Ma,
author = {Baode Ma and Tingting Miao and Yihua Sun and Yanmei He and Ziyi Yu and Yu Feng and Hui Cheng Chen and Qing-Hua Fan},
title = {A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/chem.201402709},
number = {32},
pages = {9969--9978},
doi = {10.1002/chem.201402709}
}
Cite this
MLA
Copy
Ma, Baode, et al. “A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones.” Chemistry - A European Journal, vol. 20, no. 32, Jul. 2014, pp. 9969-9978. https://doi.org/10.1002/chem.201402709.