Advanced Functional Materials, volume 19, issue 5, pages 779-788
Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells
Troshin Pavel A.
1
,
Hoppe Harald
2
,
Renz Joachim
2
,
Egginger Martin
3
,
Mayorova Julia Yu
1
,
Goryachev Andrey E
1
,
Peregudov A. S.
4
,
Lyubovskaya Rimma N.
1
,
Gobsch Gerhard
2
,
Sariciftci N. Serdar
3
,
Razumov Vladimir F.
1
2
Technical University Ilmenau, Institute of Physics Weimarer Str. 32 Ilmenau, 98693 (Germany)
|
3
Linz Institute for Organic Solar Cells (LIOS), Johannes Kepler University Linz Altenbergerstrasse 69, Linz, A‐4040 (Austria)
|
Publication type: Journal Article
Publication date: 2009-03-10
Journal:
Advanced Functional Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 19
ISSN: 1616301X
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
The preparation of 27 different derivatives of C60 and C70 fullerenes possessing various aryl (heteroaryl) and/or alkyl groups that are appended to the fullerene cage via a cyclopropane moiety and their use in bulk heterojunction polymer solar cells is reported. It is shown that even slight variations in the molecular structure of a compound can cause a significant change in its physical properties, in particular its solubility in organic solvents. Furthermore, the solubility of a fullerene derivative strongly affects the morphology of its composite with poly(3-hexylthiophene), which is commonly used as active material in bulk heterojunction organic solar cells. As a consequence, the solar cell parameters strongly depend on the structure and the properties of the fullerene-based material. The power conversion efficiencies for solar cells comprising these fullerene derivatives range from negligibly low (0.02%) to considerably high (4.1%) values. The analysis of extensive sets of experimental data reveals a general dependence of all solar cell parameters on the solubility of the fullerene derivative used as acceptor component in the photoactive layer of an organic solar cell. It is concluded that the best material combinations are those where donor and acceptor components are of similar and sufficiently high solubility in the solvent used for the deposition of the active layer.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Troshin P. A. et al. Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells // Advanced Functional Materials. 2009. Vol. 19. No. 5. pp. 779-788.
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Troshin P. A., Hoppe H., Renz J., Egginger M., Mayorova J. Yu., Goryachev A. E., Peregudov A. S., Lyubovskaya R. N., Gobsch G., Sariciftci N. S., Razumov V. F. Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells // Advanced Functional Materials. 2009. Vol. 19. No. 5. pp. 779-788.
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TY - JOUR
DO - 10.1002/adfm.200801189
UR - https://doi.org/10.1002%2Fadfm.200801189
TI - Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells
T2 - Advanced Functional Materials
AU - Renz, Joachim
AU - Egginger, Martin
AU - Mayorova, Julia Yu
AU - Goryachev, Andrey E
AU - Lyubovskaya, Rimma N.
AU - Gobsch, Gerhard
AU - Sariciftci, N. Serdar
AU - Razumov, Vladimir F.
AU - Troshin, Pavel A.
AU - Hoppe, Harald
AU - Peregudov, A. S.
PY - 2009
DA - 2009/03/10 00:00:00
PB - Wiley
SP - 779-788
IS - 5
VL - 19
SN - 1616-301X
ER -
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@article{2009_Troshin,
author = {Joachim Renz and Martin Egginger and Julia Yu Mayorova and Andrey E Goryachev and Rimma N. Lyubovskaya and Gerhard Gobsch and N. Serdar Sariciftci and Vladimir F. Razumov and Pavel A. Troshin and Harald Hoppe and A. S. Peregudov},
title = {Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells},
journal = {Advanced Functional Materials},
year = {2009},
volume = {19},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002%2Fadfm.200801189},
number = {5},
pages = {779--788},
doi = {10.1002/adfm.200801189}
}
Cite this
MLA
Copy
Troshin, Pavel A., et al. “Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells.” Advanced Functional Materials, vol. 19, no. 5, Mar. 2009, pp. 779-788. https://doi.org/10.1002%2Fadfm.200801189.
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