Unprecedented J-Aggregated Dyes in Pure Organic Solvents
H. Manzano
1
,
Ixone Esnal
1
,
Tamara Marqués Matesanz
2
,
Jorge Bañuelos
1
,
I. Lopez-Arbeloa
1
,
María L Ortiz
3
,
Luis Cerdán
4
,
Ángel Costela
4
,
Inmaculada García-Moreno
4
,
Jose Luis Chiara
2
Publication type: Journal Article
Publication date: 2016-02-25
scimago Q1
wos Q1
SJR: 5.439
CiteScore: 27.7
Impact factor: 19.0
ISSN: 1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
The design and synthesis of the first organic dyes enabling spontaneous formation of stable J-aggregates in common organic solvents without additives is described. The new dyes are O-BODIPYs with a B-spiranic 4,4-diacyloxyl substitution pattern. Key to the effectiveness of the J-aggregation process is the high conformational rigidity of the B-spiranic molecular design as well as the orthogonal disposition of the B-diacyloxyl substituent and the meso-aryl group with respect to the mean plane of the boradiazaindacene. Atomistic simulations, both in vacuum and in a solvent cage, support the dynamics of the J-aggregation process as well as its dependence on the alkylation pattern of the BODIPY chromophore. A detailed analysis of the photophysical and laser properties of the new dyes provides convincing evidence for the unambiguous assignment of these J-aggregates and their dependence on the environmental conditions.
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Metrics
62
Total citations:
62
Citations from 2024:
12
(19.35%)
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GOST
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Manzano H. et al. Unprecedented J-Aggregated Dyes in Pure Organic Solvents // Advanced Functional Materials. 2016. Vol. 26. No. 16. pp. 2756-2769.
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Manzano H., Esnal I., Marqués Matesanz T., Bañuelos J., Lopez-Arbeloa I., Ortiz M. L., Cerdán L., Costela Á., García-Moreno I., Chiara J. L. Unprecedented J-Aggregated Dyes in Pure Organic Solvents // Advanced Functional Materials. 2016. Vol. 26. No. 16. pp. 2756-2769.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adfm.201505051
UR - https://doi.org/10.1002/adfm.201505051
TI - Unprecedented J-Aggregated Dyes in Pure Organic Solvents
T2 - Advanced Functional Materials
AU - Manzano, H.
AU - Esnal, Ixone
AU - Marqués Matesanz, Tamara
AU - Bañuelos, Jorge
AU - Lopez-Arbeloa, I.
AU - Ortiz, María L
AU - Cerdán, Luis
AU - Costela, Ángel
AU - García-Moreno, Inmaculada
AU - Chiara, Jose Luis
PY - 2016
DA - 2016/02/25
PB - Wiley
SP - 2756-2769
IS - 16
VL - 26
SN - 1616-301X
SN - 1616-3028
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Manzano,
author = {H. Manzano and Ixone Esnal and Tamara Marqués Matesanz and Jorge Bañuelos and I. Lopez-Arbeloa and María L Ortiz and Luis Cerdán and Ángel Costela and Inmaculada García-Moreno and Jose Luis Chiara},
title = {Unprecedented J-Aggregated Dyes in Pure Organic Solvents},
journal = {Advanced Functional Materials},
year = {2016},
volume = {26},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/adfm.201505051},
number = {16},
pages = {2756--2769},
doi = {10.1002/adfm.201505051}
}
Cite this
MLA
Copy
Manzano, H., et al. “Unprecedented J-Aggregated Dyes in Pure Organic Solvents.” Advanced Functional Materials, vol. 26, no. 16, Feb. 2016, pp. 2756-2769. https://doi.org/10.1002/adfm.201505051.