Advanced Functional Materials, volume 31, issue 41, pages 2104863
Mechanistic Investigation of Polymer‐Based All‐Solid‐State Lithium/Sulfur Battery
Publication type: Journal Article
Publication date: 2021-07-16
Journal:
Advanced Functional Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 19
ISSN: 1616301X, 16163028
Electronic, Optical and Magnetic Materials
Electrochemistry
Condensed Matter Physics
Biomaterials
Abstract
Although employing solid polymer electrolyte (SPE) in all-solid-state lithium/sulfur (ASSLS) batteries is a promising approach to obtain a power source with both high energy density and safety, the actual performance of SPE-ASSLS batteries still lag behind conventional lithium/sulfur batteries with liquid ether electrolyte. In this work, combining characterization methods of X-ray photoelectron spectroscopy, in situ optical microscopy, and three-electrode measurement, a direct comparison between these two battery systems is made to reveal the mechanism behind their performance differences. In addition to polysulfides, it is found that the initial elemental sulfur can also dissolve into and diffuse through the SPE to reach the anode. Different from the shuttle effect that causes uniform corrosion on the anode in a liquid electrolyte, dissolved sulfur species in SPE unevenly passivate the anode surface and lead to the inhomogeneous Li+ plating/stripping at the anode/SPE solid-solid interface. Such inhomogeneity eventually causes void formation at the interface, which leads to the failure of SPE-ASSLS batteries. Based on this understanding, a protection interlayer is designed to inhibit the shuttling of sulfur species, and the modified SPE-ASSLS batteries show much-improved performance in cycle life.
Top-30
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1 publication, 3.03%
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Citations by publishers
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Wiley
11 publications, 33.33%
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6 publications, 18.18%
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5 publications, 15.15%
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Springer Nature
2 publications, 6.06%
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American Chemical Society (ACS)
2 publications, 6.06%
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OAE Publishing Inc.
2 publications, 6.06%
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Higher Education Press
1 publication, 3.03%
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Nonferrous Metals Society of China
1 publication, 3.03%
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American Association for the Advancement of Science (AAAS)
1 publication, 3.03%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 3.03%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 3.03%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Liu Y. et al. Mechanistic Investigation of Polymer‐Based All‐Solid‐State Lithium/Sulfur Battery // Advanced Functional Materials. 2021. Vol. 31. No. 41. p. 2104863.
GOST all authors (up to 50)
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Liu Y., Liu H., LIN Y., Zhao Y., Yuan H., Su Y., Zhang J., Ren S., Fan H., Zhang Y. Mechanistic Investigation of Polymer‐Based All‐Solid‐State Lithium/Sulfur Battery // Advanced Functional Materials. 2021. Vol. 31. No. 41. p. 2104863.
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TY - JOUR
DO - 10.1002/adfm.202104863
UR - https://doi.org/10.1002/adfm.202104863
TI - Mechanistic Investigation of Polymer‐Based All‐Solid‐State Lithium/Sulfur Battery
T2 - Advanced Functional Materials
AU - Liu, Haowen
AU - LIN, YITAO
AU - Zhao, Yuxing
AU - Su, Yipeng
AU - Zhang, Jifang
AU - Ren, Shuaiyang
AU - Zhang, Yuegang
AU - Liu, Yang
AU - Yuan, Hua
AU - Fan, HaiYan
PY - 2021
DA - 2021/07/16 00:00:00
PB - Wiley
SP - 2104863
IS - 41
VL - 31
SN - 1616-301X
SN - 1616-3028
ER -
Cite this
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@article{2021_Liu,
author = {Haowen Liu and YITAO LIN and Yuxing Zhao and Yipeng Su and Jifang Zhang and Shuaiyang Ren and Yuegang Zhang and Yang Liu and Hua Yuan and HaiYan Fan},
title = {Mechanistic Investigation of Polymer‐Based All‐Solid‐State Lithium/Sulfur Battery},
journal = {Advanced Functional Materials},
year = {2021},
volume = {31},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/adfm.202104863},
number = {41},
pages = {2104863},
doi = {10.1002/adfm.202104863}
}
Cite this
MLA
Copy
Liu, Yang, et al. “Mechanistic Investigation of Polymer‐Based All‐Solid‐State Lithium/Sulfur Battery.” Advanced Functional Materials, vol. 31, no. 41, Jul. 2021, p. 2104863. https://doi.org/10.1002/adfm.202104863.