volume 30 issue 44 pages 1803075

Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries

Tetsuya Asano 1
Akihiro Sakai 1
Satoru Ohuchi 1
Masashi Sakaida 1
Akinobu Miyazaki 1
Shinya Hasegawa 1
Publication typeJournal Article
Publication date2018-09-14
scimago Q1
wos Q1
SJR8.851
CiteScore39.4
Impact factor26.8
ISSN09359648, 15214095
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
New lithium halide solid-electrolyte materials, Li3 YCl6 and Li3 YBr6 , are found to exhibit high lithium-ion conductivity, high deformability, and high chemical and electrochemical stability, which are required properties for all-solid-state battery (ASSB) applications, particularly for large-scale deployment. The lithium-ion conductivities of cold-pressed powders surpass 1 mS cm-1 at room temperature without additional intergrain or grain boundary resistances. Bulk-type ASSB cells employing these new halide solid electrolyte materials exhibit coulombic efficiencies as high as 94% with an active cathode material of LiCoO2 without any extra coating. These superior electrochemical characteristics, as well as their material stability, indicate that lithium halide salts are another promising candidate for ASSB solid electrolytes in addition to sulfides or oxides.
Found 
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GOST Copy
Asano T. et al. Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries // Advanced Materials. 2018. Vol. 30. No. 44. p. 1803075.
GOST all authors (up to 50) Copy
Asano T., Sakai A., Ohuchi S., Sakaida M., Miyazaki A., Hasegawa S. Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries // Advanced Materials. 2018. Vol. 30. No. 44. p. 1803075.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adma.201803075
UR - https://doi.org/10.1002/adma.201803075
TI - Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries
T2 - Advanced Materials
AU - Asano, Tetsuya
AU - Sakai, Akihiro
AU - Ohuchi, Satoru
AU - Sakaida, Masashi
AU - Miyazaki, Akinobu
AU - Hasegawa, Shinya
PY - 2018
DA - 2018/09/14
PB - Wiley
SP - 1803075
IS - 44
VL - 30
PMID - 30216562
SN - 0935-9648
SN - 1521-4095
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Asano,
author = {Tetsuya Asano and Akihiro Sakai and Satoru Ohuchi and Masashi Sakaida and Akinobu Miyazaki and Shinya Hasegawa},
title = {Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries},
journal = {Advanced Materials},
year = {2018},
volume = {30},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/adma.201803075},
number = {44},
pages = {1803075},
doi = {10.1002/adma.201803075}
}
MLA
Cite this
MLA Copy
Asano, Tetsuya, et al. “Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries.” Advanced Materials, vol. 30, no. 44, Sep. 2018, p. 1803075. https://doi.org/10.1002/adma.201803075.