Advanced Materials, pages 2110423

Filler‐Integrated Composite Polymer Electrolyte for Solid‐State Lithium Batteries

Shuailei Liu ¹

Wenyi Liu ¹

Deliang Ba ²

Yongzhi Zhao ¹

Yihua Ye ¹

Yuanyuan Li ²

Jinping Liu ^{1, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

School of Chemistry Chemical Engineering and Life Science, and State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan Hubei 430070 P. R. China |

School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 P. R. China |

State Center for International Cooperation on Designer Low‐carbon & Environmental Materials and School of Materials Science and Engineering Zhengzhou University Zhengzhou Henan 450001 P. R. China |

Publication type: Journal Article

Publication date: 2022-08-10

Wiley

Journal: Advanced Materials

Quartile SCImago

Quartile WOS

Impact factor: 29.4

ISSN: 09359648, 15214095

DOI: 10.1002/adma.202110423

Copy DOI

General Materials Science

Mechanical Engineering

Mechanics of Materials

Abstract

Composite polymer electrolytes (CPEs) utilizing fillers as the promoting component bridge the gap between solid polymer electrolytes and inorganic solid electrolytes. The integration of fillers into the polymer matrices has been demonstrated as a prevailing strategy to enhance Li-ion transport and assist in constructing Li+-conducting electrode-electrolyte interface layer, which addresses the two key barriers of solid-state lithium batteries (SSLBs): low ionic conductivity of electrolyte and high interfacial impedance. Recent review articles have largely focused on the performance of a broad spectrum of CPEs and the general effects of fillers on SSLBs device. Recognizing this, in this review, after briefly presenting the categories of fillers (traditional and emerged) and the promoted ionic conducting mechanisms in CPEs, we seek to assess the progress in the interfacial structure design principle, with the emphasis on the crucial influence of filler size, concentration and hybridization strategies on filler-polymer interface that is the most critical to Li-ion transport. The latest exciting advances on filler-enabled in-situ generation of a Li+-conductive layer at the electrode-electrolyte interface to greatly reduce the interfacial impedance are further elaborated. Finally, we discuss the challenges to be addressed, outline research directions and provide a future vision for developing advanced CPEs for high-performing SSLBs. This article is protected by copyright. All rights reserved

By date By citations

Top-30

Citations by journals

	2 4 6 8 10 12
Advanced Materials	Advanced Materials, 11, 6.15% Advanced Materials 11 publications, 6.15%
Advanced Energy Materials	Advanced Energy Materials, 10, 5.59% Advanced Energy Materials 10 publications, 5.59%
Chemical Engineering Journal	Chemical Engineering Journal, 9, 5.03% Chemical Engineering Journal 9 publications, 5.03%
Advanced Functional Materials	Advanced Functional Materials, 8, 4.47% Advanced Functional Materials 8 publications, 4.47%
Small	Small, 6, 3.35% Small 6 publications, 3.35%
ACS applied materials & interfaces	ACS applied materials & interfaces, 5, 2.79% ACS applied materials & interfaces 5 publications, 2.79%
Nano-Micro Letters	Nano-Micro Letters, 5, 2.79% Nano-Micro Letters 5 publications, 2.79%
Journal of Energy Chemistry	Journal of Energy Chemistry, 5, 2.79% Journal of Energy Chemistry 5 publications, 2.79%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 5, 2.79% Angewandte Chemie - International Edition 5 publications, 2.79%
Journal of Energy Storage	Journal of Energy Storage, 5, 2.79% Journal of Energy Storage 5 publications, 2.79%
Angewandte Chemie	Angewandte Chemie, 5, 2.79% Angewandte Chemie 5 publications, 2.79%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 4, 2.23% Materials Chemistry Frontiers 4 publications, 2.23%
Interdisciplinary Materials	Interdisciplinary Materials, 4, 2.23% Interdisciplinary Materials 4 publications, 2.23%
Molecules	Molecules, 3, 1.68% Molecules 3 publications, 1.68%
Polymers	Polymers, 3, 1.68% Polymers 3 publications, 1.68%
Ionics	Ionics, 3, 1.68% Ionics 3 publications, 1.68%
ChemElectroChem	ChemElectroChem, 3, 1.68% ChemElectroChem 3 publications, 1.68%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 3, 1.68% Journal of Colloid and Interface Science 3 publications, 1.68%
Chemical Society Reviews	Chemical Society Reviews, 3, 1.68% Chemical Society Reviews 3 publications, 1.68%
Batteries & Supercaps	Batteries & Supercaps, 3, 1.68% Batteries & Supercaps 3 publications, 1.68%
ACS Nano	ACS Nano, 3, 1.68% ACS Nano 3 publications, 1.68%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 2, 1.12% Journal of Solid State Electrochemistry 2 publications, 1.12%
Batteries	Batteries, 2, 1.12% Batteries 2 publications, 1.12%
Energy & Fuels	Energy & Fuels, 2, 1.12% Energy & Fuels 2 publications, 1.12%
Energy and Environmental Science	Energy and Environmental Science, 2, 1.12% Energy and Environmental Science 2 publications, 1.12%
Energy Storage Materials	Energy Storage Materials, 2, 1.12% Energy Storage Materials 2 publications, 1.12%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 1.12% Journal of Materials Chemistry A 2 publications, 1.12%
Advanced Science	Advanced Science, 2, 1.12% Advanced Science 2 publications, 1.12%
Journal of the American Chemical Society	Journal of the American Chemical Society, 2, 1.12% Journal of the American Chemical Society 2 publications, 1.12%
	2 4 6 8 10 12

Citations by publishers

	10 20 30 40 50 60 70 80
Wiley	Wiley, 71, 39.66% Wiley 71 publications, 39.66%
Elsevier	Elsevier, 37, 20.67% Elsevier 37 publications, 20.67%
American Chemical Society (ACS)	American Chemical Society (ACS), 19, 10.61% American Chemical Society (ACS) 19 publications, 10.61%
Springer Nature	Springer Nature, 17, 9.5% Springer Nature 17 publications, 9.5%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 15, 8.38% Royal Society of Chemistry (RSC) 15 publications, 8.38%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 11, 6.15% Multidisciplinary Digital Publishing Institute (MDPI) 11 publications, 6.15%
OAE Publishing Inc.	OAE Publishing Inc., 2, 1.12% OAE Publishing Inc. 2 publications, 1.12%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 0.56% American Institute of Physics (AIP) 1 publication, 0.56%
Walter de Gruyter	Walter de Gruyter, 1, 0.56% Walter de Gruyter 1 publication, 0.56%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 0.56% American Association for the Advancement of Science (AAAS) 1 publication, 0.56%
IOP Publishing	IOP Publishing, 1, 0.56% IOP Publishing 1 publication, 0.56%
American Scientific Publishers	American Scientific Publishers, 1, 0.56% American Scientific Publishers 1 publication, 0.56%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.56% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.56%
	10 20 30 40 50 60 70 80

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024,2025],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[2,68,107,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["1.12","37.99","59.78","1.12"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Advanced Materials","Advanced Energy Materials","Chemical Engineering Journal","Advanced Functional Materials","Small","ACS applied materials & interfaces","Nano-Micro Letters","Journal of Energy Chemistry","Angewandte Chemie - International Edition","Journal of Energy Storage","Angewandte Chemie","Materials Chemistry Frontiers","Interdisciplinary Materials","Molecules","Polymers","Ionics","ChemElectroChem","Journal of Colloid and Interface Science","Chemical Society Reviews","Batteries & Supercaps","ACS Nano","Journal of Solid State Electrochemistry","Batteries","Energy & Fuels","Energy and Environmental Science","Energy Storage Materials","Journal of Materials Chemistry A","Advanced Science","Journal of the American Chemical Society"],"ids":[25159,22475,16275,7715,9872,1458,7765,20653,19215,18623,25450,7063,30049,1770,11204,12191,22483,24202,20586,26456,8724,10804,19798,10347,10138,3858,14919,4130,4813],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[11,10,9,8,6,5,5,5,5,5,5,4,4,3,3,3,3,3,3,3,3,2,2,2,2,2,2,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[6.15,5.59,5.03,4.47,3.35,2.79,2.79,2.79,2.79,2.79,2.79,2.23,2.23,1.68,1.68,1.68,1.68,1.68,1.68,1.68,1.68,1.12,1.12,1.12,1.12,1.12,1.12,1.12,1.12],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Elsevier","American Chemical Society (ACS)","Springer Nature","Royal Society of Chemistry (RSC)","Multidisciplinary Digital Publishing Institute (MDPI)","OAE Publishing Inc.","American Institute of Physics (AIP)","Walter de Gruyter","American Association for the Advancement of Science (AAAS)","IOP Publishing","American Scientific Publishers","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[11,17,40,8,123,202,7181,250,4,189,2075,679,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/0oGA3odz6rRHYyWD8vQnHiPJ8KIaP1PtNoJm7RE1_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/3SpVxcYL33bOvPq4sHxJLH2NeKNeDloahSUpNiO4_medium.webp","\/storage\/images\/resized\/s10mcsCV4OAUg9O2KrqOquQC0PhyLMI8hUUkuflM_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/3RKsjkHc38X9y2xwqEEGp02jSMcYwvDgfDB3LdnI_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[71,37,19,17,15,11,2,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[39.66,20.67,10.61,9.5,8.38,6.15,1.12,0.56,0.56,0.56,0.56,0.56,0.56],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024,2025],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0],"percentage":["0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1,0],"percentage":["0","0","0.56","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,6,7,0],"percentage":["0","3.35","3.91","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,56,90,0],"percentage":["1.12","31.28","50.28","0"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,6,9,2],"percentage":["0","3.35","5.03","1.12"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024,2025],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,1,2,0],"percentage":["0","0.56","1.12","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,2,2,0],"percentage":["0","1.12","1.12","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,10,11,0],"percentage":["0","5.59","6.15","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,47,81,0],"percentage":["1.12","26.26","45.25","0"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,8,11,2],"percentage":["0","4.47","6.15","1.12"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Liu S. et al. Filler‐Integrated Composite Polymer Electrolyte for Solid‐State Lithium Batteries // Advanced Materials. 2022. p. 2110423.

GOST all authors (up to 50) Copy

Liu S., Liu W., Ba D., Zhao Y., Ye Y., Li Y., Liu J. Filler‐Integrated Composite Polymer Electrolyte for Solid‐State Lithium Batteries // Advanced Materials. 2022. p. 2110423.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/adma.202110423

UR - https://doi.org/10.1002/adma.202110423

TI - Filler‐Integrated Composite Polymer Electrolyte for Solid‐State Lithium Batteries

T2 - Advanced Materials

AU - Liu, Shuailei

AU - Liu, Wenyi

AU - Ba, Deliang

AU - Zhao, Yongzhi

AU - Ye, Yihua

AU - Li, Yuanyuan

AU - Liu, Jinping

PY - 2022

DA - 2022/08/10 00:00:00

PB - Wiley

SP - 2110423

SN - 0935-9648

SN - 1521-4095

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Liu,

author = {Shuailei Liu and Wenyi Liu and Deliang Ba and Yongzhi Zhao and Yihua Ye and Yuanyuan Li and Jinping Liu},

title = {Filler‐Integrated Composite Polymer Electrolyte for Solid‐State Lithium Batteries},

journal = {Advanced Materials},

year = {2022},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/adma.202110423},

pages = {2110423},

doi = {10.1002/adma.202110423}

}

Found error?

Publisher

Wiley

Journal

Advanced Materials

Quartile SCImago

Quartile WOS

Impact factor

29.4

ISSN

09359648 (Print)
15214095 (Electronic)