Synthesis and Applications of HexaPHEMP, a Novel Biaryl Diphosphine Ligand
Julian P. Henschke
1
,
Mark J. Burk
2
,
Christophe G Malan
2
,
Daniela Herzberg
1
,
Justine A. Peterson
1
,
Andrew J Wildsmith
1
,
Christopher J. Cobley
1
,
Guy Casy
1
1
Pharmaceutical Services, Chirotech Technology Limited (a Subsidiary of The Dow Chemical Company), 321 Cambridge Science Park, Milton Road, Cambridge, CB4 0WG, UK Fax: (+44)-1223-506-701
|
2
Pharmaceutical Services, Chirotech Technology Limited (a Subsidiary of The Dow Chemical Company), 321 Cambridge Science Park, Milton Road, Cambridge, CB4 0WG, UK Fax: (+44)‐1223‐506‐701
|
Publication type: Journal Article
Publication date: 2003-01-24
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
The novel biaryldiphosphine ligand 1 (Hexa- PHEMP) has been prepared in five steps from commercially available 3,4,5-trimethylphenol using a concise synthetic route. This approach also allows fine tuning of the ligand×s stereoelectronic properties through the variation of the aromatic groups on the ligating phosphorus atoms. In certain asymmetric hydrogenation processes, catalysts containing this ligand were found to have enhanced activity and selectivity over other biaryldiphosphine-containing catalysts.
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106
Total citations:
106
Citations from 2024:
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(1.88%)
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GOST
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Henschke J. P. et al. Synthesis and Applications of HexaPHEMP, a Novel Biaryl Diphosphine Ligand // Advanced Synthesis and Catalysis. 2003. Vol. 345. No. 12. pp. 300-307.
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Henschke J. P., Burk M. J., Malan C. G., Herzberg D., Peterson J. A., Wildsmith A. J., Cobley C. J., Casy G. Synthesis and Applications of HexaPHEMP, a Novel Biaryl Diphosphine Ligand // Advanced Synthesis and Catalysis. 2003. Vol. 345. No. 12. pp. 300-307.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.200390025
UR - https://doi.org/10.1002/adsc.200390025
TI - Synthesis and Applications of HexaPHEMP, a Novel Biaryl Diphosphine Ligand
T2 - Advanced Synthesis and Catalysis
AU - Henschke, Julian P.
AU - Burk, Mark J.
AU - Malan, Christophe G
AU - Herzberg, Daniela
AU - Peterson, Justine A.
AU - Wildsmith, Andrew J
AU - Cobley, Christopher J.
AU - Casy, Guy
PY - 2003
DA - 2003/01/24
PB - Wiley
SP - 300-307
IS - 12
VL - 345
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Henschke,
author = {Julian P. Henschke and Mark J. Burk and Christophe G Malan and Daniela Herzberg and Justine A. Peterson and Andrew J Wildsmith and Christopher J. Cobley and Guy Casy},
title = {Synthesis and Applications of HexaPHEMP, a Novel Biaryl Diphosphine Ligand},
journal = {Advanced Synthesis and Catalysis},
year = {2003},
volume = {345},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adsc.200390025},
number = {12},
pages = {300--307},
doi = {10.1002/adsc.200390025}
}
Cite this
MLA
Copy
Henschke, Julian P., et al. “Synthesis and Applications of HexaPHEMP, a Novel Biaryl Diphosphine Ligand.” Advanced Synthesis and Catalysis, vol. 345, no. 12, Jan. 2003, pp. 300-307. https://doi.org/10.1002/adsc.200390025.