Advanced Synthesis and Catalysis, volume 349, issue 1-2, pages 193-203

Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes

Michał Barbasiewicz 1, 2
Michał Bieniek 2
Anna Michrowska 3, 4
Anna Szadkowska 2
Anna Makal 5
Krzysztof Woźniak 5
Publication typeJournal Article
Publication date2007-01-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.4
ISSN16154150, 16154169
General Chemistry
Abstract
Structural modifications of the Hoveyda-Grubbs ruthenium metathesis complex via electronic and structural withdrawing of the chelating alkoxy ligand were investigated. By decreasing the donor properties of the oxygen atom, an acceleration in catalytic activity was achieved based on facilitation of the initiation step. Conformational constraints of the chelating ether linkage led to the unexpected disturbance of the complex geometry and a vast improvement of the activity.

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GOST Copy
Barbasiewicz M. et al. Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes // Advanced Synthesis and Catalysis. 2007. Vol. 349. No. 1-2. pp. 193-203.
GOST all authors (up to 50) Copy
Barbasiewicz M., Bieniek M., Michrowska A., Szadkowska A., Makal A., Woźniak K., Grela K. Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes // Advanced Synthesis and Catalysis. 2007. Vol. 349. No. 1-2. pp. 193-203.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adsc.200600478
UR - https://doi.org/10.1002/adsc.200600478
TI - Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes
T2 - Advanced Synthesis and Catalysis
AU - Barbasiewicz, Michał
AU - Bieniek, Michał
AU - Michrowska, Anna
AU - Szadkowska, Anna
AU - Makal, Anna
AU - Woźniak, Krzysztof
AU - Grela, Karol
PY - 2007
DA - 2007/01/08 00:00:00
PB - Wiley
SP - 193-203
IS - 1-2
VL - 349
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex Copy
@article{2007_Barbasiewicz,
author = {Michał Barbasiewicz and Michał Bieniek and Anna Michrowska and Anna Szadkowska and Anna Makal and Krzysztof Woźniak and Karol Grela},
title = {Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes},
journal = {Advanced Synthesis and Catalysis},
year = {2007},
volume = {349},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adsc.200600478},
number = {1-2},
pages = {193--203},
doi = {10.1002/adsc.200600478}
}
MLA
Cite this
MLA Copy
Barbasiewicz, Michał, et al. “Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes.” Advanced Synthesis and Catalysis, vol. 349, no. 1-2, Jan. 2007, pp. 193-203. https://doi.org/10.1002/adsc.200600478.
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