Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes
Тип публикации: Journal Article
Дата публикации: 2007-01-08
scimago Q1
wos Q1
БС1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Краткое описание
Structural modifications of the Hoveyda-Grubbs ruthenium metathesis complex via electronic and structural withdrawing of the chelating alkoxy ligand were investigated. By decreasing the donor properties of the oxygen atom, an acceleration in catalytic activity was achieved based on facilitation of the initiation step. Conformational constraints of the chelating ether linkage led to the unexpected disturbance of the complex geometry and a vast improvement of the activity.
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Barbasiewicz M. et al. Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes // Advanced Synthesis and Catalysis. 2007. Vol. 349. No. 1-2. pp. 193-203.
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Barbasiewicz M., Bieniek M., Michrowska A., Szadkowska A., Makal A., Woźniak K., Grela K. Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes // Advanced Synthesis and Catalysis. 2007. Vol. 349. No. 1-2. pp. 193-203.
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TY - JOUR
DO - 10.1002/adsc.200600478
UR - https://doi.org/10.1002/adsc.200600478
TI - Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes
T2 - Advanced Synthesis and Catalysis
AU - Barbasiewicz, Michał
AU - Bieniek, Michał
AU - Michrowska, Anna
AU - Szadkowska, Anna
AU - Makal, Anna
AU - Woźniak, Krzysztof
AU - Grela, Karol
PY - 2007
DA - 2007/01/08
PB - Wiley
SP - 193-203
IS - 1-2
VL - 349
SN - 1615-4150
SN - 1615-4169
ER -
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@article{2007_Barbasiewicz,
author = {Michał Barbasiewicz and Michał Bieniek and Anna Michrowska and Anna Szadkowska and Anna Makal and Krzysztof Woźniak and Karol Grela},
title = {Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes},
journal = {Advanced Synthesis and Catalysis},
year = {2007},
volume = {349},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adsc.200600478},
number = {1-2},
pages = {193--203},
doi = {10.1002/adsc.200600478}
}
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MLA
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Barbasiewicz, Michał, et al. “Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes.” Advanced Synthesis and Catalysis, vol. 349, no. 1-2, Jan. 2007, pp. 193-203. https://doi.org/10.1002/adsc.200600478.