Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos
1
Stratingh Institute for Chemistry
2
DSM Pharmaceut Prod Innovat Synth & Catalysis
Publication type: Journal Article
Publication date: 2009-10-28
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
A catalyst made in situ from the (cyclooctadiene)iridium chloride dimer, [Ir(COD)Cl](2), and the monodentate phosphoramidite ligand (S)-PipPhos was used in the enantioselective hydrogenation of 2- and 2,6-substituted quinoxalines. In the presence of piperidine hydrochloride as additive full conversions and enantioselectivities of up to 96% are obtained.
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100
Total citations:
100
Citations from 2024:
8
(8%)
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GOST
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Mršić N. et al. Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos // Advanced Synthesis and Catalysis. 2009. Vol. 351. No. 16. pp. 2549-2552.
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Mršić N., Jerphagnon T., Minnaard A. J., Feringa B. L., de Vries J. G. Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos // Advanced Synthesis and Catalysis. 2009. Vol. 351. No. 16. pp. 2549-2552.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.200900522
UR - https://doi.org/10.1002/adsc.200900522
TI - Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos
T2 - Advanced Synthesis and Catalysis
AU - Mršić, Nataša
AU - Jerphagnon, Thomas
AU - Minnaard, Adriaan J.
AU - Feringa, Ben L.
AU - de Vries, Johannes G.
PY - 2009
DA - 2009/10/28
PB - Wiley
SP - 2549-2552
IS - 16
VL - 351
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Mršić,
author = {Nataša Mršić and Thomas Jerphagnon and Adriaan J. Minnaard and Ben L. Feringa and Johannes G. de Vries},
title = {Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos},
journal = {Advanced Synthesis and Catalysis},
year = {2009},
volume = {351},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/adsc.200900522},
number = {16},
pages = {2549--2552},
doi = {10.1002/adsc.200900522}
}
Cite this
MLA
Copy
Mršić, Nataša, et al. “Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos.” Advanced Synthesis and Catalysis, vol. 351, no. 16, Oct. 2009, pp. 2549-2552. https://doi.org/10.1002/adsc.200900522.