volume 351 issue 17 pages 2855-2875

Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length

Publication typeJournal Article
Publication date2009-11-18
scimago Q1
wos Q1
SJR0.930
CiteScore8.0
Impact factor4.0
ISSN16154150, 16154169
General Chemistry
Abstract
A series of furan-yne substrates with an arylalkynylamide substructure were prepared and subjected to catalytic amounts of phosphanegold(I) complexes. With two carbon atoms in the tether between the arylalkynylamide and the furan subunits, the formation of benzoanellated heterocycles was observed, a number of interesting heterocyclic framworks could be accessed in this way. With three carbon atoms in the tether, the outcome was quite different, cyclopentadiene derivatives anellated to tetrahydropyridine rings were isolated. The two different pathways suggested are supported by calculations regarding the selectivity-determining step.
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Hashmi A. et al. Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length // Advanced Synthesis and Catalysis. 2009. Vol. 351. No. 17. pp. 2855-2875.
GOST all authors (up to 50) Copy
Hashmi A., Pankajakshan S., Rudolph M., Enns E., Bander T., Rominger F., Frey W. Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length // Advanced Synthesis and Catalysis. 2009. Vol. 351. No. 17. pp. 2855-2875.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adsc.200900614
UR - https://doi.org/10.1002/adsc.200900614
TI - Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length
T2 - Advanced Synthesis and Catalysis
AU - Hashmi, A.
AU - Pankajakshan, Sreekumar
AU - Rudolph, Matthias
AU - Enns, Elisabeth
AU - Bander, Thomas
AU - Rominger, Frank
AU - Frey, Wolfgang
PY - 2009
DA - 2009/11/18
PB - Wiley
SP - 2855-2875
IS - 17
VL - 351
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Hashmi,
author = {A. Hashmi and Sreekumar Pankajakshan and Matthias Rudolph and Elisabeth Enns and Thomas Bander and Frank Rominger and Wolfgang Frey},
title = {Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length},
journal = {Advanced Synthesis and Catalysis},
year = {2009},
volume = {351},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/adsc.200900614},
number = {17},
pages = {2855--2875},
doi = {10.1002/adsc.200900614}
}
MLA
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MLA Copy
Hashmi, A., et al. “Gold Catalysis: Anellated Heterocycles and Dependency of the Reaction Pathway on the Tether Length.” Advanced Synthesis and Catalysis, vol. 351, no. 17, Nov. 2009, pp. 2855-2875. https://doi.org/10.1002/adsc.200900614.