Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols
Jian Yang
1, 2, 3
,
Xin Liu
4, 5
,
Da Li Meng
3
,
Hong-Yan Chen
4, 5
,
Zhi Hui Zong
4, 5
,
Ting-Ting Feng
4, 5
,
Kai Sun
4, 5
2
phone: (+86)-431-8561-9152
5
phone: (+86)‐431‐8561‐9152
Publication type: Journal Article
Publication date: 2012-02-09
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
The efficient iron-catalyzed direct β-alkylation of secondary alcohols with primary alcohols is described. In the presence of the commercially available iron catalyst (ferrocenecarboxaldehyde, 1b) and a catalytic amount of base, the reactions give β-alkylated higher alcohols in high yields in the absence of any sacrificial agents (hydrogen acceptors or hydrogen donors) and nitrogen or phosphorus ligands. For the first time, iron is employed as an inexpensive and environmentally benign alternative with high atom efficiency to noble metal-based catalysts in this type of reaction.
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93
Total citations:
93
Citations from 2024:
9
(9%)
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MLA
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GOST
Copy
Yang J. et al. Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols // Advanced Synthesis and Catalysis. 2012. Vol. 354. No. 2-3. pp. 328-334.
GOST all authors (up to 50)
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Yang J., Liu X., Meng D. L., Chen H., Zong Z. H., Feng T., Sun K. Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols // Advanced Synthesis and Catalysis. 2012. Vol. 354. No. 2-3. pp. 328-334.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.201000907
UR - https://doi.org/10.1002/adsc.201000907
TI - Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols
T2 - Advanced Synthesis and Catalysis
AU - Yang, Jian
AU - Liu, Xin
AU - Meng, Da Li
AU - Chen, Hong-Yan
AU - Zong, Zhi Hui
AU - Feng, Ting-Ting
AU - Sun, Kai
PY - 2012
DA - 2012/02/09
PB - Wiley
SP - 328-334
IS - 2-3
VL - 354
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Yang,
author = {Jian Yang and Xin Liu and Da Li Meng and Hong-Yan Chen and Zhi Hui Zong and Ting-Ting Feng and Kai Sun},
title = {Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols},
journal = {Advanced Synthesis and Catalysis},
year = {2012},
volume = {354},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/adsc.201000907},
number = {2-3},
pages = {328--334},
doi = {10.1002/adsc.201000907}
}
Cite this
MLA
Copy
Yang, Jian, et al. “Efficient Iron-Catalyzed Direct β-Alkylation of Secondary Alcohols with Primary Alcohols.” Advanced Synthesis and Catalysis, vol. 354, no. 2-3, Feb. 2012, pp. 328-334. https://doi.org/10.1002/adsc.201000907.