Advanced Synthesis and Catalysis, volume 353, issue 8, pages 1359-1366
A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids
1
Organic Chemistry Group
Publication type: Journal Article
Publication date: 2011-05-17
Journal:
Advanced Synthesis and Catalysis
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 1.020
CiteScore: 9.4
Impact factor: 4.4
ISSN: 16154150, 16154169
General Chemistry
Abstract
Gold(I) salts are found to mediate the de- carboxylation of a variety of aromatic and heteroaro- matic carboxylic acids at significatively lower tem- peratures (as low as 608C) than the currently used copper(I) (180-1908C) and silver(I) (80-1408C) sys- tems. In contrast to silver(I)- and copper(I)-mediated decarboxylations, the resulting aryl-gold(I) com- plexes are stable towards protodemetallation and can be readily isolated.
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Cornella J., Rosillo-Lopez M., Larrosa I. A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids // Advanced Synthesis and Catalysis. 2011. Vol. 353. No. 8. pp. 1359-1366.
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Cornella J., Rosillo-Lopez M., Larrosa I. A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids // Advanced Synthesis and Catalysis. 2011. Vol. 353. No. 8. pp. 1359-1366.
Cite this
RIS
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TY - JOUR
DO - 10.1002/adsc.201100109
UR - https://doi.org/10.1002/adsc.201100109
TI - A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids
T2 - Advanced Synthesis and Catalysis
AU - Cornella, Josep
AU - Rosillo-Lopez, Martin
AU - Larrosa, Igor
PY - 2011
DA - 2011/05/17
PB - Wiley
SP - 1359-1366
IS - 8
VL - 353
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
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Copy
@article{2011_Cornella,
author = {Josep Cornella and Martin Rosillo-Lopez and Igor Larrosa},
title = {A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids},
journal = {Advanced Synthesis and Catalysis},
year = {2011},
volume = {353},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/adsc.201100109},
number = {8},
pages = {1359--1366},
doi = {10.1002/adsc.201100109}
}
Cite this
MLA
Copy
Cornella, Josep, et al. “A Novel Mode of Reactivity for Gold(I): The Decarboxylative Activation of (Hetero)Aromatic Carboxylic Acids.” Advanced Synthesis and Catalysis, vol. 353, no. 8, May. 2011, pp. 1359-1366. https://doi.org/10.1002/adsc.201100109.