volume 356 issue 4 pages 771-780

Unprecedented control of selectivity in Nickel-catalyzed hydrophosphorylation of alkynes: Efficient route to mono- and bisphosphonates

Publication typeJournal Article
Publication date2014-03-03
scimago Q1
wos Q1
SJR0.930
CiteScore8.0
Impact factor4.0
ISSN16154150, 16154169
General Chemistry
Abstract
Received: February 3, 2014; Published online: March 3, 2014Dedicated to the memory of Z. A. Starikova.Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/adsc.201400123.Abstract: A unique nickel-based catalytic system wasdeveloped where the direction of the hydrophos-phorylation reaction can be controlled by varyingthe catalyst loading. A flexible one-pot access to vi-nylmonophosphonates and alkylbisphosphonates wasdemonstrated using simple starting materials in anatom-economic reaction without any specific solventsor ligands. Monitoring of the reaction mechanismwith joint NMR and MS studies revealed key infor-mation about the reaction intermediates. The syn-thetic scope of the developed catalytic system wasexplored and the utility of the synthesized productsfor the fire protection of cotton materials was dem-onstrated.Keywords: alkynes; homogeneous catalysis; nickel;phosphorylation; selectivity
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Khemchyan L. L. et al. Unprecedented control of selectivity in Nickel-catalyzed hydrophosphorylation of alkynes: Efficient route to mono- and bisphosphonates // Advanced Synthesis and Catalysis. 2014. Vol. 356. No. 4. pp. 771-780.
GOST all authors (up to 50) Copy
Khemchyan L. L., Ivanova J. V., S. Zalesskiy S., Ananikov V. P., Beletskaya I. P., Starikova Z. A. Unprecedented control of selectivity in Nickel-catalyzed hydrophosphorylation of alkynes: Efficient route to mono- and bisphosphonates // Advanced Synthesis and Catalysis. 2014. Vol. 356. No. 4. pp. 771-780.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adsc.201400123
UR - https://doi.org/10.1002/adsc.201400123
TI - Unprecedented control of selectivity in Nickel-catalyzed hydrophosphorylation of alkynes: Efficient route to mono- and bisphosphonates
T2 - Advanced Synthesis and Catalysis
AU - Khemchyan, Levon L
AU - Ivanova, Julia V
AU - S. Zalesskiy, Sergey
AU - Ananikov, Valentine P.
AU - Beletskaya, Irina P.
AU - Starikova, Zoya A.
PY - 2014
DA - 2014/03/03
PB - Wiley
SP - 771-780
IS - 4
VL - 356
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Khemchyan,
author = {Levon L Khemchyan and Julia V Ivanova and Sergey S. Zalesskiy and Valentine P. Ananikov and Irina P. Beletskaya and Zoya A. Starikova},
title = {Unprecedented control of selectivity in Nickel-catalyzed hydrophosphorylation of alkynes: Efficient route to mono- and bisphosphonates},
journal = {Advanced Synthesis and Catalysis},
year = {2014},
volume = {356},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/adsc.201400123},
number = {4},
pages = {771--780},
doi = {10.1002/adsc.201400123}
}
MLA
Cite this
MLA Copy
Khemchyan, Levon L., et al. “Unprecedented control of selectivity in Nickel-catalyzed hydrophosphorylation of alkynes: Efficient route to mono- and bisphosphonates.” Advanced Synthesis and Catalysis, vol. 356, no. 4, Mar. 2014, pp. 771-780. https://doi.org/10.1002/adsc.201400123.