, volume 357 , issue 2-3 , pages 417-429

The palladium slow-release pre-catalysts and nanoparticles in the "phosphine-free" Mizoroki-Heck and Suzuki-Miyaura reactions

Alexander S. Sigeev ^{1, 2, 3}

A. S. Peregudov ⁴

Andrei Cheprakov ^{2, 3}

Irina P. Beletskaya ^{2, 3}

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A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Vavilova str. 28, V-344, 119991 Moscow, Russia |

Moscow State University, Chemistry Department, Leninskie Gory, 119992 Moscow, Russia, Fax: (+7)‐499‐135‐5085 |

phone: (+7)‐495‐939‐3618

⁴

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Vavilova str. 28, V‐344, 119991 Moscow, Russia |

Publication type: Journal Article

Publication date: 2015-01-22

Wiley

Advanced Synthesis and Catalysis

scimago Q1

wos Q1

SJR: 0.930

CiteScore: 8.0

Impact factor: 4.0

ISSN: 16154150, 16154169

DOI: 10.1002/adsc.201400562

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General Chemistry

Abstract

The Mizoroki–Heck reaction of electron-rich aryl iodides was studied using a phosphine-free catalytic system with a broad range of pre-catalysts of varied stability and structure based on organoselenium chelators. The application of the “mercury test” by observing the response of the catalytic systems studied not only to the addition, but also to the withdrawal of Hg allowed us to establish a critical role of nanoparticles in the operation of the phosphine-free catalytic systems. A three-stage mechanistic scheme involving a slow stage served by mononuclear Pd species, and the main fast stage served by Pd nanoparticles, and terminated by the nanoparticle decay is proposed as a general mechanistic paradigm for the phosphine-free Mizoroki–Heck and the related Suzuki–Miyaura reactions.

Found

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Sigeev A. S. et al. The palladium slow-release pre-catalysts and nanoparticles in the "phosphine-free" Mizoroki-Heck and Suzuki-Miyaura reactions // Advanced Synthesis and Catalysis. 2015. Vol. 357. No. 2-3. pp. 417-429.

GOST all authors (up to 50) Copy

Sigeev A. S., Peregudov A. S., Cheprakov A., Beletskaya I. P. The palladium slow-release pre-catalysts and nanoparticles in the "phosphine-free" Mizoroki-Heck and Suzuki-Miyaura reactions // Advanced Synthesis and Catalysis. 2015. Vol. 357. No. 2-3. pp. 417-429.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/adsc.201400562

UR - https://doi.org/10.1002/adsc.201400562

TI - The palladium slow-release pre-catalysts and nanoparticles in the "phosphine-free" Mizoroki-Heck and Suzuki-Miyaura reactions

T2 - Advanced Synthesis and Catalysis

AU - Sigeev, Alexander S.

AU - Peregudov, A. S.

AU - Cheprakov, Andrei

AU - Beletskaya, Irina P.

PY - 2015

DA - 2015/01/22

PB - Wiley

SP - 417-429

IS - 2-3

VL - 357

SN - 1615-4150

SN - 1615-4169

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2015_Sigeev,

author = {Alexander S. Sigeev and A. S. Peregudov and Andrei Cheprakov and Irina P. Beletskaya},

title = {The palladium slow-release pre-catalysts and nanoparticles in the "phosphine-free" Mizoroki-Heck and Suzuki-Miyaura reactions},

journal = {Advanced Synthesis and Catalysis},

year = {2015},

volume = {357},

publisher = {Wiley},

month = {jan},

url = {https://doi.org/10.1002/adsc.201400562},

number = {2-3},

pages = {417--429},

doi = {10.1002/adsc.201400562}

}

MLA

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MLA Copy

Sigeev, Alexander S., et al. “The palladium slow-release pre-catalysts and nanoparticles in the "phosphine-free" Mizoroki-Heck and Suzuki-Miyaura reactions.” Advanced Synthesis and Catalysis, vol. 357, no. 2-3, Jan. 2015, pp. 417-429. https://doi.org/10.1002/adsc.201400562.

Publisher

Wiley

Journal

Advanced Synthesis and Catalysis

scimago Q1

wos Q1

SJR

0.930

CiteScore

8.0

Impact factor

4.0

ISSN

16154150 (Print)

16154169 (Electronic)

Profiles

Irina P Beletskaya