volume 358 issue 5 pages 724-730

Double‐Oxidative Dehydrogenative (DOD) Cyclization of Glycine Derivatives with Dioxane under Metal‐Free Aerobic Conditions

Congde Huo
Haisheng Xie
Fengjuan Chen
Jing Tang
Yajun Wang
Publication typeJournal Article
Publication date2016-02-15
scimago Q1
wos Q1
SJR0.930
CiteScore8.0
Impact factor4.0
ISSN16154150, 16154169
General Chemistry
Abstract
The first carbon tetrabromide-promoted novel double-oxidative dehydrogenative cyclization/acidic ring opening/aromatization tandem reaction of glycine derivatives with dioxane for the synthesis of complex quinoline motifs has been developed (up to 71% yield). The use of very inexpensive substrates (glycine derivatives and dioxane) and an extremely simple metal-free promoter (carbon tetrabromide) with green molecular oxygen (air) as an oxidant make this protocol very attractive for potential synthetic applications. A plausible mechanism involving a radical process is proposed.
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GOST Copy
Huo C. et al. Double‐Oxidative Dehydrogenative (DOD) Cyclization of Glycine Derivatives with Dioxane under Metal‐Free Aerobic Conditions // Advanced Synthesis and Catalysis. 2016. Vol. 358. No. 5. pp. 724-730.
GOST all authors (up to 50) Copy
Huo C., Xie H., Chen F., Tang J., Wang Y. Double‐Oxidative Dehydrogenative (DOD) Cyclization of Glycine Derivatives with Dioxane under Metal‐Free Aerobic Conditions // Advanced Synthesis and Catalysis. 2016. Vol. 358. No. 5. pp. 724-730.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/adsc.201500893
UR - https://doi.org/10.1002/adsc.201500893
TI - Double‐Oxidative Dehydrogenative (DOD) Cyclization of Glycine Derivatives with Dioxane under Metal‐Free Aerobic Conditions
T2 - Advanced Synthesis and Catalysis
AU - Huo, Congde
AU - Xie, Haisheng
AU - Chen, Fengjuan
AU - Tang, Jing
AU - Wang, Yajun
PY - 2016
DA - 2016/02/15
PB - Wiley
SP - 724-730
IS - 5
VL - 358
SN - 1615-4150
SN - 1615-4169
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Huo,
author = {Congde Huo and Haisheng Xie and Fengjuan Chen and Jing Tang and Yajun Wang},
title = {Double‐Oxidative Dehydrogenative (DOD) Cyclization of Glycine Derivatives with Dioxane under Metal‐Free Aerobic Conditions},
journal = {Advanced Synthesis and Catalysis},
year = {2016},
volume = {358},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/adsc.201500893},
number = {5},
pages = {724--730},
doi = {10.1002/adsc.201500893}
}
MLA
Cite this
MLA Copy
Huo, Congde, et al. “Double‐Oxidative Dehydrogenative (DOD) Cyclization of Glycine Derivatives with Dioxane under Metal‐Free Aerobic Conditions.” Advanced Synthesis and Catalysis, vol. 358, no. 5, Feb. 2016, pp. 724-730. https://doi.org/10.1002/adsc.201500893.