Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization
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Syngenta; Jealott's Hill Research Centre, Bracknell; Berkshire RG42 6EX U.K.
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Publication type: Journal Article
Publication date: 2016-07-11
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
A simple alkylamine [(iPr)2NEt] has been used to activate an air- and moisture-stable iron(II) pre-catalyst for alkene and alkyne hydrofunctionalization reactions. This amine activation has enabled the highly operationally simple hydrosilylation and hydroboration of alkenes and alkynes using just 0.25–2 mol% iron catalyst and 1–25 mol% amine. Significantly, these reactions proceed in equal yield under both air and inert reaction conditions.
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Total citations:
76
Citations from 2024:
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(17.11%)
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MLA
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GOST
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Challinor A. J. et al. Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization // Advanced Synthesis and Catalysis. 2016. Vol. 358. No. 15. pp. 2404-2409.
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Challinor A. J., Calin M., Nichol G. S., Carter N. B., Thomas S. P. Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization // Advanced Synthesis and Catalysis. 2016. Vol. 358. No. 15. pp. 2404-2409.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.201600570
UR - https://doi.org/10.1002/adsc.201600570
TI - Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization
T2 - Advanced Synthesis and Catalysis
AU - Challinor, Amy J
AU - Calin, Marc
AU - Nichol, Gary S.
AU - Carter, Neil B
AU - Thomas, Stephen P.
PY - 2016
DA - 2016/07/11
PB - Wiley
SP - 2404-2409
IS - 15
VL - 358
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Challinor,
author = {Amy J Challinor and Marc Calin and Gary S. Nichol and Neil B Carter and Stephen P. Thomas},
title = {Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization},
journal = {Advanced Synthesis and Catalysis},
year = {2016},
volume = {358},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/adsc.201600570},
number = {15},
pages = {2404--2409},
doi = {10.1002/adsc.201600570}
}
Cite this
MLA
Copy
Challinor, Amy J., et al. “Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization.” Advanced Synthesis and Catalysis, vol. 358, no. 15, Jul. 2016, pp. 2404-2409. https://doi.org/10.1002/adsc.201600570.