Iridium‐Catalyzed Enantioselective Hydrogenation of Vinylsilanes
Publication type: Journal Article
Publication date: 2017-03-15
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
We have screened a diverse array of iridium complexes derived from chiral N,P ligands as catalysts for the asymmetric hydrogenation of vinylsilanes, a transformation for which generally applicable catalysts were lacking. Several catalysts emerged from this study that enabled the highly enantioselective hydrogenation of a wide range of vinylsilanes with trisubstituted or disubstituted terminal C=C bonds bearing aryl, alkyl, ethoxycarbonyl, or hydroxymethyl substituents. In addition to trimethylsilyl and dimethyl(phenyl)silyl derivatives, trialkoxysilyl- and silacyclobutyl-substituted alkenes were used as substrates.
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Metrics
17
Total citations:
17
Citations from 2024:
2
(11.76%)
Cite this
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MLA
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GOST
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Wang A. et al. Iridium‐Catalyzed Enantioselective Hydrogenation of Vinylsilanes // Advanced Synthesis and Catalysis. 2017. Vol. 359. No. 15. pp. 2523-2529.
GOST all authors (up to 50)
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Wang A., Bernasconi M., Pfaltz A. Iridium‐Catalyzed Enantioselective Hydrogenation of Vinylsilanes // Advanced Synthesis and Catalysis. 2017. Vol. 359. No. 15. pp. 2523-2529.
Cite this
RIS
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TY - JOUR
DO - 10.1002/adsc.201700162
UR - https://doi.org/10.1002/adsc.201700162
TI - Iridium‐Catalyzed Enantioselective Hydrogenation of Vinylsilanes
T2 - Advanced Synthesis and Catalysis
AU - Wang, Aie
AU - Bernasconi, Maurizio
AU - Pfaltz, A.
PY - 2017
DA - 2017/03/15
PB - Wiley
SP - 2523-2529
IS - 15
VL - 359
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Wang,
author = {Aie Wang and Maurizio Bernasconi and A. Pfaltz},
title = {Iridium‐Catalyzed Enantioselective Hydrogenation of Vinylsilanes},
journal = {Advanced Synthesis and Catalysis},
year = {2017},
volume = {359},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/adsc.201700162},
number = {15},
pages = {2523--2529},
doi = {10.1002/adsc.201700162}
}
Cite this
MLA
Copy
Wang, Aie, et al. “Iridium‐Catalyzed Enantioselective Hydrogenation of Vinylsilanes.” Advanced Synthesis and Catalysis, vol. 359, no. 15, Mar. 2017, pp. 2523-2529. https://doi.org/10.1002/adsc.201700162.