Advanced Synthesis and Catalysis, volume 363, issue 8, pages 1970-1997
Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts
Publication type: Journal Article
Publication date: 2021-01-20
Journal:
Advanced Synthesis and Catalysis
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 1.020
CiteScore: 9.4
Impact factor: 4.4
ISSN: 16154150, 16154169
General Chemistry
Abstract
This review article summarizes reports for Z-selective olefin metathesis reactions by molybdenum, tungsten, ruthenium, and vanadium catalysts. It is clearly demonstrated that the ligand modifications play essential roles in achieving the stereospecific olefin metathesis reactions. In particular, Mo- and W-alkylidene based complex catalysts having pyrrolide-aryloxide [or bis(aryloxide)] were highly effective in the efficient enantioselective ring opening/cross-metathesis (EROCM), cross metathesis (CM), homodimerization, ring-opening metathesis polymerization (ROMP), and in ring closing metathesis (RCM) with high Z- selectivities (∼>98%). Ruthenium-carbene catalysts having cycloadamantyl, catechothiolate, phenolate and thiophenolate ligands display pronounced Z-selectivity (>98%) in efficient CM, ROCM, AROCM, RCM, ROMP reactions. Halogenated (arylimido)-alkoxo vanadium-alkylidenes were thermally robust and effective for efficient highly cis-specific ROMP of cyclic olefins to afford end-functionalized ring-opened polymers.
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Dawood K. M., Nomura K. Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts // Advanced Synthesis and Catalysis. 2021. Vol. 363. No. 8. pp. 1970-1997.
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Dawood K. M., Nomura K. Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts // Advanced Synthesis and Catalysis. 2021. Vol. 363. No. 8. pp. 1970-1997.
Cite this
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TY - JOUR
DO - 10.1002/adsc.202001117
UR - https://doi.org/10.1002/adsc.202001117
TI - Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts
T2 - Advanced Synthesis and Catalysis
AU - Dawood, Kamal Mohamed
AU - Nomura, Kotohiro
PY - 2021
DA - 2021/01/20
PB - Wiley
SP - 1970-1997
IS - 8
VL - 363
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex
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@article{2021_Dawood,
author = {Kamal Mohamed Dawood and Kotohiro Nomura},
title = {Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts},
journal = {Advanced Synthesis and Catalysis},
year = {2021},
volume = {363},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/adsc.202001117},
number = {8},
pages = {1970--1997},
doi = {10.1002/adsc.202001117}
}
Cite this
MLA
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Dawood, Kamal Mohamed, and Kotohiro Nomura. “Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts.” Advanced Synthesis and Catalysis, vol. 363, no. 8, Jan. 2021, pp. 1970-1997. https://doi.org/10.1002/adsc.202001117.