Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers
Publication type: Journal Article
Publication date: 2021-05-06
scimago Q1
wos Q1
SJR: 0.930
CiteScore: 8.0
Impact factor: 4.0
ISSN: 16154150, 16154169
General Chemistry
Abstract
Bromohydrins and their ethers were electrochemically synthesized via hydroxy‐ and alkoxybromination of alkenes using potassium bromide and water or alcohols. High selectivity of bromohydrins formation was achieved only with the use of DMSO as the solvent and an acid as the additive. The proposed combination of starting reagents, additives, and solvents allowed to form bromohydrins or their ethers selectively despite the variety of side‐products (epoxides, dibromides, diols). Bromohydrins were obtained in high yields, up to 96%, with a broad substrate scope in an undivided electrochemical cell equipped with glassy carbon and platinum electrodes at high current density.
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32
Total citations:
32
Citations from 2024:
12
(37%)
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GOST
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Bityukov O. V. et al. Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers // Advanced Synthesis and Catalysis. 2021. Vol. 363. No. 12. pp. 3070-3078.
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Bityukov O. V., Nikishin G. I., Vil’ V. A., Terent’ev A. O. Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers // Advanced Synthesis and Catalysis. 2021. Vol. 363. No. 12. pp. 3070-3078.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/adsc.202100161
UR - https://doi.org/10.1002/adsc.202100161
TI - Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers
T2 - Advanced Synthesis and Catalysis
AU - Bityukov, Oleg V
AU - Nikishin, Gennady I.
AU - Vil’, Vera A.
AU - Terent’ev, Alexander O.
PY - 2021
DA - 2021/05/06
PB - Wiley
SP - 3070-3078
IS - 12
VL - 363
SN - 1615-4150
SN - 1615-4169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Bityukov,
author = {Oleg V Bityukov and Gennady I. Nikishin and Vera A. Vil’ and Alexander O. Terent’ev},
title = {Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers},
journal = {Advanced Synthesis and Catalysis},
year = {2021},
volume = {363},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/adsc.202100161},
number = {12},
pages = {3070--3078},
doi = {10.1002/adsc.202100161}
}
Cite this
MLA
Copy
Bityukov, Oleg V., et al. “Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers.” Advanced Synthesis and Catalysis, vol. 363, no. 12, May. 2021, pp. 3070-3078. https://doi.org/10.1002/adsc.202100161.