Advanced Energy Materials, pages 2201762

In Situ Catalytic Polymerization of a Highly Homogeneous PDOL Composite Electrolyte for Long‐Cycle High‐Voltage Solid‐State Lithium Batteries

Hua Yang ¹

Bo Zhang ²

Maoxiang Jing ¹

Xiangqian Shen ¹

Li Wang ²

Hong Xu ²

Xiaohong Yan ¹

Xiangming He ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Institute for Advanced Materials School of Materials Science and Engineering Jiangsu University Zhenjiang 212013 China |

Institute of Nuclear and New Energy Technology Tsinghua University Beijing 100084 China |

Publication type: Journal Article

Publication date: 2022-08-25

Wiley

Journal: Advanced Energy Materials

Quartile SCImago

Quartile WOS

Impact factor: 27.8

ISSN: 16146832, 16146840

DOI: 10.1002/aenm.202201762

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General Materials Science

Renewable Energy, Sustainability and the Environment

Abstract

High energy density solid-state lithium batteries require good ionic conductive solid electrolytes (SE) and stable matching with high-voltage electrode materials. Here, a highly homogeneous poly(1,3-dioxolane) composite solid electrolyte (CSE) membrane that can satisfy the above-mentioned requirements by in situ catalytic polymerization effect of yttria stabilized zirconia (YSZ) nanoparticles on the polymerization of 1,3-dioxolane (DOL), is reported. The well-dispersed YSZ nanoparticle catalyst leads to the polymerization conversion of DOL monomers up to 98.5%, which enlarges its electrochemical window exceeding 4.9 V. YSZ also significantly improves the room temperature ionic conductivity (2.75 × 10−4 S cm−1) and enhances the cycle life of lithium metal anode. Based on this CSE, the Li(Ni0.6Co0.2Mn0.2)O2 (NCM622)-based solid-state lithium battery shows a long cycle life over 800 cycles. This investigation encourages polymer SE toward practical high energy solid-state batteries.

By date By citations

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Citations by journals

	2 4 6 8 10 12
Chemical Engineering Journal	Chemical Engineering Journal, 11, 11.83% Chemical Engineering Journal 11 publications, 11.83%
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Advanced Energy Materials	Advanced Energy Materials, 6, 6.45% Advanced Energy Materials 6 publications, 6.45%
Small	Small, 5, 5.38% Small 5 publications, 5.38%
ACS Applied Energy Materials	ACS Applied Energy Materials, 4, 4.3% ACS Applied Energy Materials 4 publications, 4.3%
Advanced Materials	Advanced Materials, 4, 4.3% Advanced Materials 4 publications, 4.3%
Journal of Energy Storage	Journal of Energy Storage, 4, 4.3% Journal of Energy Storage 4 publications, 4.3%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 4, 4.3% Angewandte Chemie - International Edition 4 publications, 4.3%
Angewandte Chemie	Angewandte Chemie, 4, 4.3% Angewandte Chemie 4 publications, 4.3%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 4, 4.3% Journal of Colloid and Interface Science 4 publications, 4.3%
Nano-Micro Letters	Nano-Micro Letters, 2, 2.15% Nano-Micro Letters 2 publications, 2.15%
Interdisciplinary Materials	Interdisciplinary Materials, 2, 2.15% Interdisciplinary Materials 2 publications, 2.15%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 2.15% ACS applied materials & interfaces 2 publications, 2.15%
Solid State Ionics	Solid State Ionics, 2, 2.15% Solid State Ionics 2 publications, 2.15%
ChemSusChem	ChemSusChem, 2, 2.15% ChemSusChem 2 publications, 2.15%
ACS Nano	ACS Nano, 2, 2.15% ACS Nano 2 publications, 2.15%
Science China Chemistry	Science China Chemistry, 2, 2.15% Science China Chemistry 2 publications, 2.15%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 2, 2.15% Journal of the Electrochemical Society 2 publications, 2.15%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 1.08% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 1.08%
Small Methods	Small Methods, 1, 1.08% Small Methods 1 publication, 1.08%
ChemPlusChem	ChemPlusChem, 1, 1.08% ChemPlusChem 1 publication, 1.08%
RSC Advances	RSC Advances, 1, 1.08% RSC Advances 1 publication, 1.08%
Energy & Fuels	Energy & Fuels, 1, 1.08% Energy & Fuels 1 publication, 1.08%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 1.08% Journal of Alloys and Compounds 1 publication, 1.08%
Energy and Environmental Science	Energy and Environmental Science, 1, 1.08% Energy and Environmental Science 1 publication, 1.08%
Frontiers in Energy Research	Frontiers in Energy Research, 1, 1.08% Frontiers in Energy Research 1 publication, 1.08%
Macromolecules	Macromolecules, 1, 1.08% Macromolecules 1 publication, 1.08%
Carbon Energy	Carbon Energy, 1, 1.08% Carbon Energy 1 publication, 1.08%
Polymers	Polymers, 1, 1.08% Polymers 1 publication, 1.08%
Advanced Nanocomposites	Advanced Nanocomposites, 1, 1.08% Advanced Nanocomposites 1 publication, 1.08%
	2 4 6 8 10 12

Citations by publishers

	5 10 15 20 25 30 35 40 45
Wiley	Wiley, 45, 48.39% Wiley 45 publications, 48.39%
Elsevier	Elsevier, 27, 29.03% Elsevier 27 publications, 29.03%
American Chemical Society (ACS)	American Chemical Society (ACS), 10, 10.75% American Chemical Society (ACS) 10 publications, 10.75%
Springer Nature	Springer Nature, 4, 4.3% Springer Nature 4 publications, 4.3%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 2.15% Royal Society of Chemistry (RSC) 2 publications, 2.15%
The Electrochemical Society	The Electrochemical Society, 2, 2.15% The Electrochemical Society 2 publications, 2.15%
Frontiers Media S.A.	Frontiers Media S.A., 1, 1.08% Frontiers Media S.A. 1 publication, 1.08%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 1.08% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 1.08%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.08% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.08%
	5 10 15 20 25 30 35 40 45

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Yang H. et al. In Situ Catalytic Polymerization of a Highly Homogeneous PDOL Composite Electrolyte for Long‐Cycle High‐Voltage Solid‐State Lithium Batteries // Advanced Energy Materials. 2022. p. 2201762.

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Yang H., Zhang B., Jing M., Shen X., Wang L., Xu H., Yan X., He X. In Situ Catalytic Polymerization of a Highly Homogeneous PDOL Composite Electrolyte for Long‐Cycle High‐Voltage Solid‐State Lithium Batteries // Advanced Energy Materials. 2022. p. 2201762.

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RIS Copy

TY - JOUR

DO - 10.1002/aenm.202201762

UR - https://doi.org/10.1002/aenm.202201762

TI - In Situ Catalytic Polymerization of a Highly Homogeneous PDOL Composite Electrolyte for Long‐Cycle High‐Voltage Solid‐State Lithium Batteries

T2 - Advanced Energy Materials

AU - Jing, Maoxiang

AU - Shen, Xiangqian

AU - Yang, Hua

AU - He, Xiangming

AU - Zhang, Bo

AU - Wang, Li

AU - Xu, Hong

AU - Yan, Xiaohong

PY - 2022

DA - 2022/08/25 00:00:00

PB - Wiley

SP - 2201762

SN - 1614-6832

SN - 1614-6840

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Yang,

author = {Maoxiang Jing and Xiangqian Shen and Hua Yang and Xiangming He and Bo Zhang and Li Wang and Hong Xu and Xiaohong Yan},

title = {In Situ Catalytic Polymerization of a Highly Homogeneous PDOL Composite Electrolyte for Long‐Cycle High‐Voltage Solid‐State Lithium Batteries},

journal = {Advanced Energy Materials},

year = {2022},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/aenm.202201762},

pages = {2201762},

doi = {10.1002/aenm.202201762}

}

Found error?

Publisher

Wiley

Journal

Advanced Energy Materials

Quartile SCImago

Quartile WOS

Impact factor

27.8

ISSN

16146832 (Print)
16146840 (Electronic)