Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding
M. A. Kinzhalov
1
,
Maria V Kashina
1
,
Ekaterina A Mozheeva
1
,
Andrey S Smirnov
1
,
Daniil M Ivanov
1
,
Mariya A Kryukova
1
,
Aleksandr Yu Ivanov
1
,
Sergej N Smirnov
1
,
Vadim Yu. Kukushkin
1, 2
,
Konstantin Luzyanin
1, 3
Publication type: Journal Article
Publication date: 2018-08-29
General Medicine
Abstract
In the current study, we evaluated the solubility of a number of organometallic species and showed that it is noticeably improved in diiodomethane when compared to other haloalkane solvents. The better solvation properties of CH2I2 were associated with the substantially better σ‐hole‐donating ability of this solvent, which results in the formation of uniquely strong solvent–(metal complex) halogen bonding. The strength of the halogen bonding is attenuated by the introduction of additional halogen atoms in the organometallic species owing to the competitive formation of more favourable intermolecular complex–complex halogen bonding. The exceptional solvation properties of diiodomethane and its inertness towards organometallic species make this solvent a good candidate for NMR studies, in particular, for the acquisition of spectra of insensitive spins.
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13
Total citations:
13
Citations from 2025:
2
(15.38%)
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Kinzhalov M. A. et al. Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding // Angewandte Chemie. 2018. Vol. 130. No. 39. pp. 12967-12971.
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Kinzhalov M. A., Kashina M. V., Mikherdov A., Mozheeva E. A., Novikov A. S., Smirnov A. S., Ivanov D. M., Kryukova M. A., Ivanov A. Yu., Smirnov S. N., Kukushkin V. Y., Luzyanin K. Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding // Angewandte Chemie. 2018. Vol. 130. No. 39. pp. 12967-12971.
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TY - JOUR
DO - 10.1002/ange.201807642
UR - https://onlinelibrary.wiley.com/doi/10.1002/ange.201807642
TI - Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding
T2 - Angewandte Chemie
AU - Kinzhalov, M. A.
AU - Kashina, Maria V
AU - Mikherdov, Alexander
AU - Mozheeva, Ekaterina A
AU - Novikov, Alexander S.
AU - Smirnov, Andrey S
AU - Ivanov, Daniil M
AU - Kryukova, Mariya A
AU - Ivanov, Aleksandr Yu
AU - Smirnov, Sergej N
AU - Kukushkin, Vadim Yu.
AU - Luzyanin, Konstantin
PY - 2018
DA - 2018/08/29
PB - Wiley
SP - 12967-12971
IS - 39
VL - 130
SN - 0044-8249
SN - 1521-3757
ER -
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BibTex (up to 50 authors)
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@article{2018_Kinzhalov,
author = {M. A. Kinzhalov and Maria V Kashina and Alexander Mikherdov and Ekaterina A Mozheeva and Alexander S. Novikov and Andrey S Smirnov and Daniil M Ivanov and Mariya A Kryukova and Aleksandr Yu Ivanov and Sergej N Smirnov and Vadim Yu. Kukushkin and Konstantin Luzyanin},
title = {Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding},
journal = {Angewandte Chemie},
year = {2018},
volume = {130},
publisher = {Wiley},
month = {aug},
url = {https://onlinelibrary.wiley.com/doi/10.1002/ange.201807642},
number = {39},
pages = {12967--12971},
doi = {10.1002/ange.201807642}
}
Cite this
MLA
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Kinzhalov, M. A., et al. “Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding.” Angewandte Chemie, vol. 130, no. 39, Aug. 2018, pp. 12967-12971. https://onlinelibrary.wiley.com/doi/10.1002/ange.201807642.