volume 26, issue 8, pages 771-773
A 1-Oxa-2-nickela-5-cyclopentanone from Ethene and Carbon Dioxide: Preparation, Structure, and Reactivity
Publication type: Journal Article
Publication date: 1987-08-01
—
General Chemistry
Catalysis
Abstract
Complex 1 is a key intermediate in the Ni0-promoted CC bond formation between alkenes and CO2; it contains 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as ligand. The NiC bond of 1 can participate in further, regioselective insertion reactions with alkenes. The nickelacycle is thus a model complex for the study of Ni-catalyzed reactions.
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