том 27 , издание 12 , страницы 1715-1716

Arylmino(halogeno)phosphanes XPNC6H2tBu3 (X Cl, Br, I) and the Iminophosphenium Tetrachloroaluminate [PNC6H2tBu3]⊕[AlCl4]⊖: the First Stable Compound with a PN Triple Bond

Тип публикации: Journal Article

Дата публикации: 1988-12-01

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DOI: 10.1002/anie.198817151

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General Chemistry

Catalysis

Краткое описание

The cation 4 can be obtained in an amazingly simple raction sequence from phosphorus trichloride 1 and the arylamine 2 via the iminophosphane 3. Spectroscopic findings—δ(31P) = 79.3—and structural data—PNC angle = 177°, PN distance = 147.5 pm—suggest the presence of a triple bond, whereby 4 is isoelectronic with :SiN–aryl.

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Angewandte Chemie	Angewandte Chemie, 12, 9.68% Angewandte Chemie 12 публикаций, 9.68%
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Phosphorus, Sulfur and Silicon and the Related Elements	Phosphorus, Sulfur and Silicon and the Related Elements, 7, 5.65% Phosphorus, Sulfur and Silicon and the Related Elements 7 публикаций, 5.65%
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