Catalytic Functionalization of Hydrocarbons by σ-Bond-Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst
Aaron D. Sadow
1
,
Publication type: Journal Article
Publication date: 2003-02-17
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
12596205
General Chemistry
Catalysis
Abstract
C–H activation with scandium: Reaction of [CpScCH3] (1, Cp*=C5Me5) with MesSiH3 (Mes=2,4,6-C6H2Me3) yielded a new scandium silyl complex [CpScSiH2Mes] (2) by an unusual σ-bond metathesis pathway. Complex 2 activates the CH bonds of benzene and methane. In the presence of excess Ph2SiH2, the catalytic dehydrosilation of saturated and unsaturated hydrocarbons, including methane, was accomplished, with [CpScH] (see scheme; R=CH3, C3H5, CHCMe2) which can be formed from 1 or 2. This appears to be the first example of catalytic methane functionalization by σ-bond metathesis.
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129
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Citations from 2025:
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Sadow A. D., Tilley T. D. Catalytic Functionalization of Hydrocarbons by σ-Bond-Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst // Angewandte Chemie - International Edition. 2003. Vol. 42. No. 7. pp. 803-805.
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Sadow A. D., Tilley T. D. Catalytic Functionalization of Hydrocarbons by σ-Bond-Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst // Angewandte Chemie - International Edition. 2003. Vol. 42. No. 7. pp. 803-805.
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TY - JOUR
DO - 10.1002/anie.200390213
UR - https://doi.org/10.1002/anie.200390213
TI - Catalytic Functionalization of Hydrocarbons by σ-Bond-Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst
T2 - Angewandte Chemie - International Edition
AU - Sadow, Aaron D.
AU - Tilley, T. Don
PY - 2003
DA - 2003/02/17
PB - Wiley
SP - 803-805
IS - 7
VL - 42
PMID - 12596205
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2003_Sadow,
author = {Aaron D. Sadow and T. Don Tilley},
title = {Catalytic Functionalization of Hydrocarbons by σ-Bond-Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst},
journal = {Angewandte Chemie - International Edition},
year = {2003},
volume = {42},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.200390213},
number = {7},
pages = {803--805},
doi = {10.1002/anie.200390213}
}
Cite this
MLA
Copy
Sadow, Aaron D., and T. Don Tilley. “Catalytic Functionalization of Hydrocarbons by σ-Bond-Metathesis Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst.” Angewandte Chemie - International Edition, vol. 42, no. 7, Feb. 2003, pp. 803-805. https://doi.org/10.1002/anie.200390213.