Angewandte Chemie - International Edition, volume 43, issue 48, pages 6676-6680

Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6]

Ralf Haiges 1
Jerry A Boatz 2
Ashwani Vij 2
Vandana Vij 2
Michael Gerken 1
Stefan Schneider 1
Thorsten Schroer 1
Muhammed Yousufuddin 1
Karl O. Christe 1
2
 
Space and Missile Propulsion Division, Air Force Research Laboratory (AFRL/PRSP), 10 East Saturn Boulevard Bldg 8451, Edwards Air Force Base, CA 93524, USA
Publication typeJournal Article
Publication date2004-12-10
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor16.6
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
After all, neat As(N3)5 can be isolated: By analogy with AsCl5, neat As(N3)5 was predicted to be a highly unstable compound, and previous attempts at its synthesis had resulted in intense explosions. The successful syntheses and characterization of neat As(N3)5 and Sb(N3)5 and the crystal structure of the [Sb(N3)6]− ion (see picture) are now described.

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GOST |
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GOST Copy
Haiges R. et al. Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6] // Angewandte Chemie - International Edition. 2004. Vol. 43. No. 48. pp. 6676-6680.
GOST all authors (up to 50) Copy
Haiges R., Boatz J. A., Vij A., Vij V., Gerken M., Schneider S., Schroer T., Yousufuddin M., Christe K. O. Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6] // Angewandte Chemie - International Edition. 2004. Vol. 43. No. 48. pp. 6676-6680.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.200461730
UR - https://doi.org/10.1002/anie.200461730
TI - Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6]
T2 - Angewandte Chemie - International Edition
AU - Haiges, Ralf
AU - Boatz, Jerry A
AU - Vij, Ashwani
AU - Vij, Vandana
AU - Gerken, Michael
AU - Schneider, Stefan
AU - Schroer, Thorsten
AU - Yousufuddin, Muhammed
AU - Christe, Karl O.
PY - 2004
DA - 2004/12/10 00:00:00
PB - Wiley
SP - 6676-6680
IS - 48
VL - 43
SN - 1433-7851
SN - 1521-3773
ER -
BibTex |
Cite this
BibTex Copy
@article{2004_Haiges,
author = {Ralf Haiges and Jerry A Boatz and Ashwani Vij and Vandana Vij and Michael Gerken and Stefan Schneider and Thorsten Schroer and Muhammed Yousufuddin and Karl O. Christe},
title = {Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6]},
journal = {Angewandte Chemie - International Edition},
year = {2004},
volume = {43},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/anie.200461730},
number = {48},
pages = {6676--6680},
doi = {10.1002/anie.200461730}
}
MLA
Cite this
MLA Copy
Haiges, Ralf, et al. “Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6].” Angewandte Chemie - International Edition, vol. 43, no. 48, Dec. 2004, pp. 6676-6680. https://doi.org/10.1002/anie.200461730.
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