Angewandte Chemie - International Edition, volume 44, issue 12, pages 1860-1865
Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions
Ralf Haiges
1
,
Jerry A Boatz
2
,
Robert Bau
1
,
Stefan Schneider
1
,
Thorsten Schroer
1
,
Muhammed Yousufuddin
1
,
Karl O. Christe
1
2
Space and Missile Propulsion Division, Air Force Research Laboratory (AFRL/PRSP), 10 East Saturn Boulevard, Edwards Air Force Base, CA 93524, USA
|
Publication type: Journal Article
Publication date: 2005-03-11
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Bang on target: The highly explosive Group 6 azides Mo(N3)6 and W(N3)6 are prepared by the reaction of Me3SiN3 with MoF6 and WF6, respectively. The structure of W(N3)6 has perfect rhombohedral C3 symmetry (see picture). The reaction of Mo(N3)6 and W(N3)6 with ionic azides leads to the formation of [Mo(N3)7]− and [W(N3)7]−, respectively, the first binary heptaazides. Controlled decomposition of these anions produces [NMo(N3)4]− and [NW(N3)4]−.
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Haiges R. et al. Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions // Angewandte Chemie - International Edition. 2005. Vol. 44. No. 12. pp. 1860-1865.
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Haiges R., Boatz J. A., Bau R., Schneider S., Schroer T., Yousufuddin M., Christe K. O. Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions // Angewandte Chemie - International Edition. 2005. Vol. 44. No. 12. pp. 1860-1865.
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TY - JOUR
DO - 10.1002/anie.200462740
UR - https://doi.org/10.1002/anie.200462740
TI - Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions
T2 - Angewandte Chemie - International Edition
AU - Haiges, Ralf
AU - Boatz, Jerry A
AU - Bau, Robert
AU - Schneider, Stefan
AU - Schroer, Thorsten
AU - Yousufuddin, Muhammed
AU - Christe, Karl O.
PY - 2005
DA - 2005/03/11 00:00:00
PB - Wiley
SP - 1860-1865
IS - 12
VL - 44
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2005_Haiges,
author = {Ralf Haiges and Jerry A Boatz and Robert Bau and Stefan Schneider and Thorsten Schroer and Muhammed Yousufuddin and Karl O. Christe},
title = {Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions},
journal = {Angewandte Chemie - International Edition},
year = {2005},
volume = {44},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/anie.200462740},
number = {12},
pages = {1860--1865},
doi = {10.1002/anie.200462740}
}
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Haiges, Ralf, et al. “Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions.” Angewandte Chemie - International Edition, vol. 44, no. 12, Mar. 2005, pp. 1860-1865. https://doi.org/10.1002/anie.200462740.