Angewandte Chemie - International Edition, volume 45, issue 29, pages 4830-4835
Experimental Evidence for Linear Metal–Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]−, and [Ta(N3)6]−, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)]
2
Space and Missile Propulsion Division, Air Force Research Laboratory (AFRL/PRSP), 10 East Saturn Boulevard Bldg 8451, Edwards Air Force Base, CA 93524, USA
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Publication type: Journal Article
Publication date: 2006-07-17
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
: Whereas the existence of numerous binary transition metal azido-complexes has been reported, no binary Group 5 azides are known. Only a limited number of partially azide-substituted compounds of vanadium, niobium and tantalum have previously been reported. In this paper, we wish to communicate the synthesis and characterization of Nb(N3)5, Ta(N3)5 and their 1:1 adducts with CH3CN, and of the anions [Nb(N3)6]- and [Ta(N3)6]-. The crystal structures of [Nb(N3)5(CH3CN)] and [PPh4][Nb(N3)6] and the first experimental evidence for the existence of azido compounds with linear metal-N-N bonds are also reported.
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Citations by publishers
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5
10
15
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35
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Wiley
31 publications, 58.49%
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1 publication, 1.89%
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5
10
15
20
25
30
35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Haiges R. et al. Experimental Evidence for Linear Metal–Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]−, and [Ta(N3)6]−, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)] // Angewandte Chemie - International Edition. 2006. Vol. 45. No. 29. pp. 4830-4835.
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Haiges R., Boatz J. A., Schroer T., Yousufuddin M., Christe K. O. Experimental Evidence for Linear Metal–Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]−, and [Ta(N3)6]−, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)] // Angewandte Chemie - International Edition. 2006. Vol. 45. No. 29. pp. 4830-4835.
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TY - JOUR
DO - 10.1002/anie.200601060
UR - https://doi.org/10.1002/anie.200601060
TI - Experimental Evidence for Linear Metal–Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]−, and [Ta(N3)6]−, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)]
T2 - Angewandte Chemie - International Edition
AU - Haiges, Ralf
AU - Boatz, Jerry A
AU - Schroer, Thorsten
AU - Yousufuddin, Muhammed
AU - Christe, Karl O.
PY - 2006
DA - 2006/07/17 00:00:00
PB - Wiley
SP - 4830-4835
IS - 29
VL - 45
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2006_Haiges,
author = {Ralf Haiges and Jerry A Boatz and Thorsten Schroer and Muhammed Yousufuddin and Karl O. Christe},
title = {Experimental Evidence for Linear Metal–Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]−, and [Ta(N3)6]−, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)]},
journal = {Angewandte Chemie - International Edition},
year = {2006},
volume = {45},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/anie.200601060},
number = {29},
pages = {4830--4835},
doi = {10.1002/anie.200601060}
}
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Haiges, Ralf, et al. “Experimental Evidence for Linear Metal–Azido Coordination: The Binary Group 5 Azides [Nb(N3)5], [Ta(N3)5], [Nb(N3)6]−, and [Ta(N3)6]−, and 1:1 Acetonitrile Adducts [Nb(N3)5(CH3CN)] and [Ta(N3)5(CH3CN)].” Angewandte Chemie - International Edition, vol. 45, no. 29, Jul. 2006, pp. 4830-4835. https://doi.org/10.1002/anie.200601060.