Angewandte Chemie - International Edition

, volume 47 , issue 2 , pages 258-297

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

Zhan Lu ¹

Sheng-Ming Ma ^{2, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China. |

Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China |

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China, Fax: (+86) 216‐416‐7510 |

Publication type: Journal Article

Publication date: 2008-01-01

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.200605113

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PubMed ID: 17968865

General Chemistry

Catalysis

Abstract

Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range of different nucleophiles or S(N)2'-type allylic substitution, leads to the formation of C-H, -C, -O, -N, -S, and other bonds with very high levels of asymmetric induction. The reaction may tolerate a broad range of functional groups and has been applied successfully to the synthesis of many natural products and new chiral compounds.

Found

46 citations

Gavrilov Konstantin

DSc in Chemistry, professor

149 publications, 1 765 citations

h-index: 20

Ryazan State University named after S. A. Esenin

Research interests

Asymmetric metal complex catalysis

Asymmetric synthesis

Complex formation

16 citations

Shiryaev Alexey

PhD in Chemistry

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University of Tyumen

Ryazan State University named after S. A. Esenin

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A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

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Organic Chemistry

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Trunina Valeria

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h-index: 5

Ryazan State University named after S. A. Esenin

Research interests

Complex formation

Organic synthesis

Synthesis of chiral phosphorus-containing ligands

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Birin Kirill

🥼 🤝

DSc in Chemistry

95 publications, 1 200 citations, 2 reviews

h-index: 19

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

MIREA — Russian Technological University

National Research University Higher School of Economics

Research interests

Catalysis

Coordination Chemistry

Green chemistry

Hybrid materials

Inorganic Chemistry

Metal-organic coordination polymers

NMR spectroscopy

Organic Chemistry

Organoelement chemistry

2 citations

Tyurin Vladimir

🥼 🤝

PhD in Chemistry

71 publications, 1 816 citations, 7 reviews

h-index: 15

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Supramolecular chemistry

1 citation

Sukhorukov Alexey

DSc in Chemistry

123 publications, 1 634 citations, 129 reviews

h-index: 22

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Medicinal Chemistry

Organic Chemistry

1 citation

Zagidullin Almaz

🥼 🤝

PhD in Chemistry

82 publications, 904 citations

h-index: 17

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Coordination chemistry of phosphorus

Organoelement chemistry

Organophosphorus chemistry

Synthesis of chiral phosphorus-containing ligands

1 citation

Nesterov Nikolay

PhD in Chemistry

20 publications, 359 citations, 1 review

h-index: 10

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

1 citation

Belova Anastasiya

🥼 🤝

PhD in Chemistry

16 publications, 185 citations

h-index: 6

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

National Research Centre "Kurchatov Institute"

Research interests

Excimer

Fluorescence

High molecular weight compounds

Luminescent materials

Organic Chemistry

Organic synthesis

Polymer science

1 citation

Temnikov Maxim

PhD in Chemistry

35 publications, 610 citations, 4 reviews

h-index: 13

Tula State Pedagogical University named after L.N. Tolstoy

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Green chemistry

High molecular weight compounds

1 citation

Philippov Alexey

🥼 🤝

PhD in Chemistry

24 publications, 270 citations, 14 reviews

h-index: 10

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

Research interests

Catalysis

Green chemistry

1 citation

Shalygin Anton

🥼 🤝

PhD in Chemistry

40 publications, 573 citations, 1 review

h-index: 13

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Evdokimenkova Yulia

PhD in Chemistry

36 publications, 231 citations

h-index: 10

Library for Natural Sciences of the Russian Academy of Sciences

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Lu Z., Ma S. Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis // Angewandte Chemie - International Edition. 2008. Vol. 47. No. 2. pp. 258-297.

GOST all authors (up to 50) Copy

Lu Z., Ma S. Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis // Angewandte Chemie - International Edition. 2008. Vol. 47. No. 2. pp. 258-297.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.200605113

UR - https://doi.org/10.1002/anie.200605113

TI - Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

T2 - Angewandte Chemie - International Edition

AU - Lu, Zhan

AU - Ma, Sheng-Ming

PY - 2008

DA - 2008/01/01

PB - Wiley

SP - 258-297

IS - 2

VL - 47

PMID - 17968865

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2008_Lu,

author = {Zhan Lu and Sheng-Ming Ma},

title = {Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis},

journal = {Angewandte Chemie - International Edition},

year = {2008},

volume = {47},

publisher = {Wiley},

month = {jan},

url = {https://doi.org/10.1002/anie.200605113},

number = {2},

pages = {258--297},

doi = {10.1002/anie.200605113}

}

MLA

Cite this

MLA Copy

Lu, Zhan, et al. “Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis.” Angewandte Chemie - International Edition, vol. 47, no. 2, Jan. 2008, pp. 258-297. https://doi.org/10.1002/anie.200605113.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)