More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions.
Publication type: Journal Article
Publication date: 2008-01-18
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
18081111
General Chemistry
Catalysis
Abstract
Olefins and alkynes are ubiquitous in transition-metal catalysis, whether introduced by the substrate, the catalyst, or as an additive. Whereas the impact of metals and ligands is relatively well understood, the effects of olefins in these reactions are generally underappreciated, even though numerous examples of olefins influencing the outcome of a reaction, through increased activity, stability, or selectivity, have been reported. This Review provides an overview of the interaction of olefins with transition metals and documents examples of olefins influencing the outcome of catalytic reactions, in particular cross-coupling reactions. It should thus provide a basis for the improved understanding and further utilization of olefin and alkyne effects in transition-metal-catalyzed reactions.
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352
Total citations:
352
Citations from 2024:
14
(3.97%)
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GOST
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Johnson J. B., Rovis T. More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. // Angewandte Chemie - International Edition. 2008. Vol. 47. No. 5. pp. 840-871.
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Johnson J. B., Rovis T. More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. // Angewandte Chemie - International Edition. 2008. Vol. 47. No. 5. pp. 840-871.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.200700278
UR - https://doi.org/10.1002/anie.200700278
TI - More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions.
T2 - Angewandte Chemie - International Edition
AU - Johnson, Jeffrey B.
AU - Rovis, Tomislav
PY - 2008
DA - 2008/01/18
PB - Wiley
SP - 840-871
IS - 5
VL - 47
PMID - 18081111
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Johnson,
author = {Jeffrey B. Johnson and Tomislav Rovis},
title = {More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions.},
journal = {Angewandte Chemie - International Edition},
year = {2008},
volume = {47},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.200700278},
number = {5},
pages = {840--871},
doi = {10.1002/anie.200700278}
}
Cite this
MLA
Copy
Johnson, Jeffrey B., and Tomislav Rovis. “More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions..” Angewandte Chemie - International Edition, vol. 47, no. 5, Jan. 2008, pp. 840-871. https://doi.org/10.1002/anie.200700278.