The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines
Publication type: Journal Article
Publication date: 2008-01-11
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
18181258
General Chemistry
Catalysis
Abstract
Building a better scaffold: Low loadings (0.2–1 mol %) of new double axially chiral phosphoric acid catalysts 1 based on bis-binol scaffold were used for asymmetric transfer hydrogenation. 2-Aryl- and 2-alkyl-substituted quinolines gave tetrahydroquinolines in excellent yields and with up to 98 % ee and 2,3-disubstituted tetrahydroquinolines were prepared in high diastereo- and enantioselectivities (up to >20:1 and 92 % ee).
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Metrics
317
Total citations:
317
Citations from 2024:
20
(6.31%)
Cite this
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MLA
Cite this
GOST
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Guo Q. The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines // Angewandte Chemie - International Edition. 2008. Vol. 47. No. 4. pp. 759-762.
GOST all authors (up to 50)
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Guo Q. The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines // Angewandte Chemie - International Edition. 2008. Vol. 47. No. 4. pp. 759-762.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.200703925
UR - https://doi.org/10.1002/anie.200703925
TI - The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines
T2 - Angewandte Chemie - International Edition
AU - Guo, Qun-sheng
PY - 2008
DA - 2008/01/11
PB - Wiley
SP - 759-762
IS - 4
VL - 47
PMID - 18181258
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Guo,
author = {Qun-sheng Guo},
title = {The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines},
journal = {Angewandte Chemie - International Edition},
year = {2008},
volume = {47},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/anie.200703925},
number = {4},
pages = {759--762},
doi = {10.1002/anie.200703925}
}
Cite this
MLA
Copy
Guo, Qun-sheng, et al. “The Development of Double Axially Chiral Phosphoric Acids and Their Catalytic Transfer Hydrogenation of Quinolines.” Angewandte Chemie - International Edition, vol. 47, no. 4, Jan. 2008, pp. 759-762. https://doi.org/10.1002/anie.200703925.