Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents
Publication type: Journal Article
Publication date: 2008-12-18
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
19040235
General Chemistry
Catalysis
Abstract
Classical protocols for carbonyl allylation, propargylation and vinylation typically rely upon the use of preformed allyl metal, allenyl metal and vinyl metal reagents, respectively, mandating stoichiometric generation of metallic byproducts. Through transfer hydrogenative CC coupling, however, carbonyl addition may be achieved from the aldehyde or alcohol oxidation level in the absence of stoichiometric organometallic reagents or metallic reductants. Here, we review transfer hydrogenative methods for carbonyl addition, which encompass the first catalytic protocols enabling direct CH functionalization of alcohols.
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Metrics
295
Total citations:
295
Citations from 2024:
12
(4.07%)
Cite this
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MLA
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GOST
Copy
Bower J. E. et al. Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents // Angewandte Chemie - International Edition. 2008. Vol. 48. No. 1. pp. 34-46.
GOST all authors (up to 50)
Copy
Bower J. E., Kim I. S., Patman R. L., Krische M. J. Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents // Angewandte Chemie - International Edition. 2008. Vol. 48. No. 1. pp. 34-46.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.200802938
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.200802938
TI - Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents
T2 - Angewandte Chemie - International Edition
AU - Bower, John Eric
AU - Kim, In Su
AU - Patman, Ryan L
AU - Krische, Michael J
PY - 2008
DA - 2008/12/18
PB - Wiley
SP - 34-46
IS - 1
VL - 48
PMID - 19040235
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Bower,
author = {John Eric Bower and In Su Kim and Ryan L Patman and Michael J Krische},
title = {Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents},
journal = {Angewandte Chemie - International Edition},
year = {2008},
volume = {48},
publisher = {Wiley},
month = {dec},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.200802938},
number = {1},
pages = {34--46},
doi = {10.1002/anie.200802938}
}
Cite this
MLA
Copy
Bower, John Eric, et al. “Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents.” Angewandte Chemie - International Edition, vol. 48, no. 1, Dec. 2008, pp. 34-46. https://onlinelibrary.wiley.com/doi/10.1002/anie.200802938.