Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality
1
Chemical Development Department, Albany Molecular Research, Inc., 21 Corporate Circle, Albany, NY 12203 (USA)
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Publication type: Journal Article
Publication date: 2009-06-29
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
19557755
General Chemistry
Catalysis
Abstract
In the past decade, palladium-catalyzed C-H activation/C-C bond-forming reactions have emerged as promising new catalytic transformations; however, development in this field is still at an early stage compared to the state of the art in cross-coupling reactions using aryl and alkyl halides. This Review begins with a brief introduction of four extensively investigated modes of catalysis for forming C-C bonds from C-H bonds: Pd(II)/Pd(0), Pd(II)/Pd(IV), Pd(0)/Pd(II)/Pd(IV), and Pd(0)/Pd(II) catalysis. A more detailed discussion is then directed towards the recent development of palladium(II)-catalyzed coupling of C-H bonds with organometallic reagents through a Pd(II)/Pd(0) catalytic cycle. Despite the progress made to date, improving the versatility and practicality of this new reaction remains a tremendous challenge.
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Chen X. et al. Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality // Angewandte Chemie - International Edition. 2009. Vol. 48. No. 28. pp. 5094-5115.
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Chen X., Engle K. M., Wang D., Yu J. Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality // Angewandte Chemie - International Edition. 2009. Vol. 48. No. 28. pp. 5094-5115.
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TY - JOUR
DO - 10.1002/anie.200806273
UR - https://doi.org/10.1002/anie.200806273
TI - Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality
T2 - Angewandte Chemie - International Edition
AU - Chen, Xiao
AU - Engle, Keary M
AU - Wang, Donghui
AU - Yu, Jinquan
PY - 2009
DA - 2009/06/29
PB - Wiley
SP - 5094-5115
IS - 28
VL - 48
PMID - 19557755
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2009_Chen,
author = {Xiao Chen and Keary M Engle and Donghui Wang and Jinquan Yu},
title = {Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality},
journal = {Angewandte Chemie - International Edition},
year = {2009},
volume = {48},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/anie.200806273},
number = {28},
pages = {5094--5115},
doi = {10.1002/anie.200806273}
}
Cite this
MLA
Copy
Chen, Xiao, et al. “Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality.” Angewandte Chemie - International Edition, vol. 48, no. 28, Jun. 2009, pp. 5094-5115. https://doi.org/10.1002/anie.200806273.