Spectroscopic Characterization of a HydroperoxoâHeme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex
Jin Gang Liu
1
,
Takehiro Ohta
1
,
Satoru Yamaguchi
2
,
T. Ogura
2
,
Satoshi Sakamoto
3
,
Yonezo Maeda
3
,
Yoshinori Naruta
1
Publication type: Journal Article
Publication date: 2009-11-23
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
19882613
General Chemistry
Catalysis
Abstract
Modeling job: Protonation of a closed seven-coordinate side-on heme peroxide can switch its spin state from high- to low-spin and convert the η2 binding fashion into a monodentate configuration to afford the corresponding hydroperoxide (see scheme). The end-on low-spin ferric hydroperoxo–heme species bear a covalently appended axial imidazole ligand and are easily prepared.
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100
Total citations:
100
Citations from 2025:
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(6%)
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GOST
Copy
Liu J. G. et al. Spectroscopic Characterization of a HydroperoxoâHeme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex // Angewandte Chemie - International Edition. 2009. Vol. 48. No. 49. pp. 9262-9267.
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Liu J. G., Ohta T., Yamaguchi S., Ogura T., Sakamoto S., Maeda Y., Naruta Y. Spectroscopic Characterization of a HydroperoxoâHeme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex // Angewandte Chemie - International Edition. 2009. Vol. 48. No. 49. pp. 9262-9267.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.200904572
UR - https://doi.org/10.1002/anie.200904572
TI - Spectroscopic Characterization of a HydroperoxoâHeme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex
T2 - Angewandte Chemie - International Edition
AU - Liu, Jin Gang
AU - Ohta, Takehiro
AU - Yamaguchi, Satoru
AU - Ogura, T.
AU - Sakamoto, Satoshi
AU - Maeda, Yonezo
AU - Naruta, Yoshinori
PY - 2009
DA - 2009/11/23
PB - Wiley
SP - 9262-9267
IS - 49
VL - 48
PMID - 19882613
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Liu,
author = {Jin Gang Liu and Takehiro Ohta and Satoru Yamaguchi and T. Ogura and Satoshi Sakamoto and Yonezo Maeda and Yoshinori Naruta},
title = {Spectroscopic Characterization of a HydroperoxoâHeme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex},
journal = {Angewandte Chemie - International Edition},
year = {2009},
volume = {48},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/anie.200904572},
number = {49},
pages = {9262--9267},
doi = {10.1002/anie.200904572}
}
Cite this
MLA
Copy
Liu, Jin Gang, et al. “Spectroscopic Characterization of a HydroperoxoâHeme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex.” Angewandte Chemie - International Edition, vol. 48, no. 49, Nov. 2009, pp. 9262-9267. https://doi.org/10.1002/anie.200904572.