Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity
U. Olsbye
1
,
Stian Svelle
2
,
Morten Bjørgen
3
,
Pablo Beato
4
,
Ton V.W. Janssens
4
,
Finn Joensen
4
,
Silvia Bordiga
5
,
K. P. Lillerud
2
4
Haldor Topsøe, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)
|
Publication type: Journal Article
Publication date: 2012-04-18
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
22511469
General Chemistry
Catalysis
Abstract
The active site of the methanol-to-hydrocarbons reaction has been identified as a hybrid site consisting of an organic molecule in close interaction with a Brønsted acidic proton on the zeolite lattice. With increasing internal volume, the organic intermediates change from alkenes via a mixture of alkenes and arenes to mainly arenes. Product selectivity reflects the site composition.
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Olsbye U. et al. Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 24. pp. 5810-5831.
GOST all authors (up to 50)
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Olsbye U., Svelle S., Bjørgen M., Beato P., Janssens T. V., Joensen F., Bordiga S., Lillerud K. P. Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity // Angewandte Chemie - International Edition. 2012. Vol. 51. No. 24. pp. 5810-5831.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201103657
UR - https://doi.org/10.1002/anie.201103657
TI - Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity
T2 - Angewandte Chemie - International Edition
AU - Olsbye, U.
AU - Svelle, Stian
AU - Bjørgen, Morten
AU - Beato, Pablo
AU - Janssens, Ton V.W.
AU - Joensen, Finn
AU - Bordiga, Silvia
AU - Lillerud, K. P.
PY - 2012
DA - 2012/04/18
PB - Wiley
SP - 5810-5831
IS - 24
VL - 51
PMID - 22511469
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Olsbye,
author = {U. Olsbye and Stian Svelle and Morten Bjørgen and Pablo Beato and Ton V.W. Janssens and Finn Joensen and Silvia Bordiga and K. P. Lillerud},
title = {Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity},
journal = {Angewandte Chemie - International Edition},
year = {2012},
volume = {51},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/anie.201103657},
number = {24},
pages = {5810--5831},
doi = {10.1002/anie.201103657}
}
Cite this
MLA
Copy
Olsbye, U., et al. “Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity.” Angewandte Chemie - International Edition, vol. 51, no. 24, Apr. 2012, pp. 5810-5831. https://doi.org/10.1002/anie.201103657.