Angewandte Chemie - International Edition, volume 50, issue 44, pages 10421-10424
Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration
Publication type: Journal Article
Publication date: 2011-09-09
Q1
Q1
SJR: 5.300
CiteScore: 26.6
Impact factor: 16.1
ISSN: 14337851, 15213773
PubMed ID:
21910200
General Chemistry
Catalysis
Abstract
The golden side of rhodium: Highly functionalized seven-membered rings were prepared from substituted cyclopropanes by a RhI-catalyzed tandem isomerization reaction. The π-acidic RhI catalyst promoted the formation of an allene intermediate by a 1,3 acyloxy migration of a propargyl ester and a subsequent net 1,5 migration of a cyclopropane CC bond.
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GOST
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Li X. et al. Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration // Angewandte Chemie - International Edition. 2011. Vol. 50. No. 44. pp. 10421-10424.
GOST all authors (up to 50)
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Li X., Zhang M., Shu D., Robichaux P. J., Huang S., Tang W. Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration // Angewandte Chemie - International Edition. 2011. Vol. 50. No. 44. pp. 10421-10424.
Cite this
RIS
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TY - JOUR
DO - 10.1002/anie.201104861
UR - https://doi.org/10.1002/anie.201104861
TI - Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration
T2 - Angewandte Chemie - International Edition
AU - Li, Xiaoxun
AU - Zhang, Min
AU - Shu, Dongxu
AU - Robichaux, Patrick J
AU - Huang, Suyu
AU - Tang, Weiping
PY - 2011
DA - 2011/09/09
PB - Wiley
SP - 10421-10424
IS - 44
VL - 50
PMID - 21910200
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Li,
author = {Xiaoxun Li and Min Zhang and Dongxu Shu and Patrick J Robichaux and Suyu Huang and Weiping Tang},
title = {Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration},
journal = {Angewandte Chemie - International Edition},
year = {2011},
volume = {50},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.201104861},
number = {44},
pages = {10421--10424},
doi = {10.1002/anie.201104861}
}
Cite this
MLA
Copy
Li, Xiaoxun, et al. “Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration.” Angewandte Chemie - International Edition, vol. 50, no. 44, Sep. 2011, pp. 10421-10424. https://doi.org/10.1002/anie.201104861.